1. | \(\Delta H\) | 2. | \(\Delta S_{Total}\) |
3. | \(\Delta S_{System}\) | 4. | \(\Delta G^o\) |
1. | 2. | ||
3. | 4. |
The work done when 1 mole of gas expands reversibly and isothermally from a pressure of 5 atm to 1 atm at 300 K is:
(Given log 5 = 0.6989 and R = 8.314 J K-1 mol-1)
1. zero J
2. 150 J
3. +4014.6 J
4.-4014.6 J
Column I | Column II | ||
(i) | Spontaneous process | (a) | Isothermal and isobaric process |
(ii) | \(\Delta H^\circ\) | (b) | \(\Delta H<0 \) |
(iii) | \(\Delta T=0, \Delta P=0 \) | (c) | \(\Delta G<0 \) |
(iv) | Exothermic process | (d) | (Bond energy of reactant) - (Bond energy of product) |
I | II | III | IV | |
1. | c | d | a | b |
2. | b | a | c | d |
3. | d | b | c | d |
4. | a | d | b | c |
Assertion (A): | The increase in internal energy \((\Delta E ) \) for the vapourisation of one mole of water at 1 atm and 373 K is zero. |
Reason (R): | For all isothermal processes, \(\Delta E = 0 \). |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True and (R) is False. |
4. | (A) and (R) both are False. |
1. | 1260 J | 2. | 2520 J |
3. | 5040 J | 4. | 0 J |
1. | In a reversible process, the system and surroundings are always in equilibrium with each other. |
2. | Work done in free expansion > 0. |
3. | \(\Delta q \) = 0 . | For adiabatic change,
4. | \(\Delta H = q_p \) | For a process carried at constant pressure,
1. | \(2.29 \times 10^4 \) | 2. | \(2.29 \times 10^{-4} \) |
3. | \(-2.29 \times 10^4 \) | 4. | \(-2.29 \times 10^{-4} \) |
1. | Molar heat capacity is an intensive property. |
2. | \(\Delta S > 0 \) for an isolated system \((\Delta U = 0 )\) |
3. | A bomb calorimeter is used to measure the heat absorbed at a constant volume. |
4. | Pressure, volume and work done on the system are state functions. |
1. | \(\Delta U = \Delta H + \Delta n_gRT \) |
2. | \(C_p - C_V = R \) for 1 mole of a non-ideal gas. |
3. | \(\Delta S_{total} > 0 \) for a spontaneous process. |
4. | \(K = ( {\Delta_r G^{0} \over RT}) \) | In