Assertion (A): | An atomic orbital is monocentric, whereas a molecular orbital is polycentric. |
Reason (R): | An electron in an atomic orbital is influenced by one nucleus whereas in a molecular orbital, it is influenced by two or more nuclei depending upon the number of atoms in a molecule. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
1. | 0 |
2. | +1 |
3. | -1 |
4. | 0 in some resonance structures, –1 in other resonance structures |
1. | PCl3 | Trigonal pyramidal |
2. | OF2 | Linear |
3. | CIF3 | Trigonal planar |
4. | SF6 | Hexagonal |
1. | \(\mathrm{AlCl_4^-}\) | 2. | \(\mathrm{CO_2}\) |
3. | \(\mathrm{PCl_4^+}\) | 4. | \(\mathrm{SO_2}\) |
1. | \(\mathrm{NH}_3 \) | 2. | \(\mathrm{R}-\mathrm{CN} ~\) |
3. | \(\mathrm{R}-\mathrm{O}-\mathrm{R} ~\) | 4. | \(\mathrm{R}-\mathrm{Br} \) |
1. | \(\pi^*\) antibonding molecular orbital has a node between the nuclei. | The
2. | In the formation of a bonding molecular orbital, the two electron waves of the bonding atoms reinforce each other. |
3. | \(2P_x\) and \(2P_y\) orbitals are symmetrical around the bond axis. | Molecular orbitals obtained from
4. | \(\pi-\)bonding molecular orbital has larger electron density above and below the internuclear axis. | A
1. | \(CH_4>H_2S>NH_3>HF \) |
2. | \(H_2S>NH_3>HF>CH_4 \) |
3. | \(NH_3>HF>CH_4>H_2~S \) |
4. | \(HF>NH_3>H_2S>CH_4\) |
1. | 1 | 2. | 3 |
3. | 2 | 4. | 4 |