The potential of hydrogen electrode in contact with a solution with pH =10, is:

If the E^o_cell for a given reaction has a negative value, which of the following gives correct relationships for the values of ∆G^o and K_eq?

1. $∆{\mathrm{G}}^{\mathrm{o}}<mspace\; width="1em"></mspace>><mspace\; width="1em"></mspace>0;<mspace\; width="1em"></mspace>{\mathrm{K}}_{\mathrm{eq}}<<mspace\; width="1em"></mspace>1$

2. $∆{\mathrm{G}}^{\mathrm{o}}<mspace\; width="1em"></mspace>><mspace\; width="1em"></mspace>0;<mspace\; width="1em"></mspace>{\mathrm{K}}_{\mathrm{eq}}><mspace\; width="1em"></mspace>1$

3. $∆{\mathrm{G}}^{\mathrm{o}}<mspace\; width="1em"></mspace><<mspace\; width="1em"></mspace>0;<mspace\; width="1em"></mspace>{\mathrm{K}}_{\mathrm{eq}}><mspace\; width="1em"></mspace>1$

4. $∆{\mathrm{G}}^{\mathrm{o}}<mspace\; width="1em"></mspace><<mspace\; width="1em"></mspace>0;<mspace\; width="1em"></mspace>{\mathrm{K}}_{\mathrm{eq}}<<mspace\; width="1em"></mspace>1$