| 1. | 31 | 2. | 49 |
| 3. | 44 | 4. | 51 |
The false statement among the following is:
| 1. | Carius tube is used in the estimation of sulphur in an organic compound |
| 2. | Carius method is used for the estimation of nitrogen in an organic compound |
| 3. | Phosphoric acid produced on oxidation of phosphorus present in an organic compound is precipitated as Mg2P2O7 by adding magnesia mixture. |
| 4. | Kjeldahl's method is used for the estimation of nitrogen in an organic compound |
In the Carius method of estimation of halogen, 0.172g of an organic compound showed the presence of 0.08g of bromine. The correct structure of the compound among the following is:
| 1. | ![]() |
2. | \(\mathrm{H}_3 \mathrm{C}-\mathrm{CH}_2-\mathrm{Br} \) |
| 3. | ![]() |
4. | \(\mathrm{H}_3 \mathrm{C}-\mathrm{Br}\) |
The Kjeldahl method of Nitrogen estimation fails for which of the following reaction products?
| 1. | 2. | ||
| 3. | 4. |
1. (a), (c) and (d)
2. (b) and (c)
3. (a) and (d)
4. (c) and (d)
In an estimation of bromine by the Carius method, 1.6 g of an organic compound gave 1.88 g of AgBr. The mass percentage of bromine in the compound is:
[Atomic mass, Ag=108, Br = 80 g ]
1. 50 %
2. 55.5%
3. 60 %
4. 70 %
Match the following:
| Test/Method | Reagent | ||
| (i) | Lucas Test | (a) | |
| (ii) | Dumas method | (b) | |
| (iii) | Kjeldahl's method | (c) | |
| (iv) | Hinsberg Test | (d) | |
| (e) |
1. (i)-(d). (ii)-(c), (iii)-(e), (iv)-(a)
2. (i)-(b), (ii)-(d), (iii)-(e), (iv)-(a)
3. (i)-(d), (ii)-(c), (iii)-(b), (iv)-(e)
4. (i)-(b), (ii)-(a), (iii)-(c), (iv)-(d)
An organic compound 'A' is oxidized with Na2O2 followed by boiling with HNO3. The resultant solution is then treated with ammonium molybdate to yield a yellow precipitate. Based on the above observation, the element present in the given compound is:
1. Fluorine
2. Phosphorus
3. Nitrogen
4. Sulphur