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| a. | The reactivity of chlorine is less than that of bromine towards alkanes. |
| b. | For the photochemical chlorination of methane, Cl is formed in the slowest step. |
| c. | Free radicals are pyramidal intermediates, stabilized by hyperconjugation and resonance. |
| d. | Bromine has much higher regioselectivity than chlorine in abstracting 3° hydrogen. |
| 1. | a, c, d | 2. | a, b, c |
| 3. | c, d, b | 4. | None of the above |
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| 1. | \(HI\) is a strong reducing agent. |
| 2. | The \(\text{H–I}\) bond is too strong to be broken homolytically. |
| 3. | The \(I\) atom combines with \(H\) atom to give back \(HI.\) |
| 4. | The iodine atom is not reactive enough to add across a double bond. |
| A. | The number of possible theoretical conformations of ethane is 6. |
| B. | In the conformations of ethane, the staggered form has the least torsional strain, and the eclipsed form has the maximum torsional strain. |
| C. | Hückel Rule: The presence of (4n + 2) π electrons in the ring where n is an integer (n = 1, 2, ......). |
| 1. | \((CH_3)_3C(CH_2)_2CH_3~~~~~~~~~~~~~\) |
| 2. | 4-isobutyl heptane |
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| a. | Benzene hexachloride is an aromatic compound. |
| b. | \(-NHCOCH_3\) is meta directing group towards aromatic electrophilic substitution reaction. |
| c. | In an arenium ion, one of the carbon is sp3 hybridised. |
| 1. | (a) and (b) only | 2. | (a) and (c) only |
| 3. | (c) only | 4. | (a), (b) and (c) |