Select the correct option based on the statements below:
Assertion (A): | The bond angle in ethers is slightly less than the angle of tetrahedral. |
Reason (R): | There is repulsion between the two bulky (— R) groups. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Select the correct option based on statements below:
Assertion (A): | The IUPAC name of the compoundis 2-ethoxy-2-methylethane. |
Reason (R): | In IUPAC nomenclature, ether is regarded as a hydrocarbon derivative in which a hydrogen atom is replaced by —OR or -OAr group [where, R = alkyl group and Ar = aryl group]. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Select the correct option based on statements below:
Assertion (A): | Ether behave as bases in the presence of mineral acids. |
Reason (R): | It is due to the presence of lone pairs of electrons on the oxygen atom. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
Match the following:
List I | List II | ||
i. | O2N-C6H5-OCH3 (p) | a. | 4-Ethoxy-1,1-dimethylcyclohexane |
ii. | C2H5OCH2-CH(CH3)2 | b. | 1-Chloro-2-methoxyethane |
iii. | CH3OCH2CH2Cl | c. | 1-Ethoxy-2-methylpropane |
iv. | d. | 1-Methoxy-4-nitrobenzene |
i | ii | iii | iv | |
1. | d | c | b | a |
2. | c | d | b | a |
3. | a | c | b | d |
4. | b | c | d | a |
Match the items of Column I with items of Column II.
Column l |
Column ll |
||
A. |
Reimer-Tiemann reaction |
1. |
Conversion of phenol to o-hydroxysalicylic aid |
B. |
Kolbe's reaction |
2. |
Heated copper at 573K |
C. |
Conversion of 2alcohol to a ketone |
3. |
Reaction of an alkyl halide |
D. |
Williamson's synthesis |
4. |
Conversion of phenol to salicylaldehyde |
Codes:
A | B | C | D | |
1. | 2 | 3 | 4 | 1 |
2. | 3 | 4 | 1 | 2 |
3. | 1 | 4 | 3 | 2 |
4. | 4 | 1 | 2 | 3 |
Match the starting material in Column I with the products formed (Column II) in the reaction with HI.
Column I |
Column II |
||
A. | 1. | ||
B. | 2. | ||
C. | 3. | ||
D. | 4. | ||
5. |
A | B | C | D | |
1. | 2 | 3 | 4 | 1 |
2. | 3 | 1 | 5 | 2 |
3. | 5 | 4 | 3 | 2 |
4. | 4 | 5 | 2 | 1 |