The following equilibrium constants are given:
N2 + 3H2 ⇌ 2NH3; K1
N2 + O2 ⇌ 2NO; K2
H2 + 1/2O2 ⇌ H2O; K3
The equilibrium constant for the oxidation of NH3 by oxygen to give NO is:
1.
2.
3.
4.
Which composition will make the basic buffer?
1. | 100 mL of 0.1 M HCl+100 mL of 0.1 M NaOH |
2. | 50 mL of 0.1 M NaOH+25 mL of 0.1 M CH3COOH |
3. | 100 mL of 0.1 M CH3COOH+100 mL of 0.1 M NaOH |
4. | 100 mL of 0.1 M HCl+200 mL of 0.1 M NH4OH |
pH of a saturated solution of is 9. The solubility product of is:
1.
2.
3.
4.
1. H3O+ and H2F+, respectively.
2. OH– and H2F+, respectively.
3. H3O+ and F–, respectively.
4. OH– and F–, respectively.
In a buffer solution containing an equal concentration of B- and HB, the Kb for B- is 10-10. pH of the buffer solution is:
1. | 10 | 2. | 7 |
3. | 6 | 4. | 4 |
The value of for the reaction is less than zero. Formation of will be favoured at:
1. Low pressure and low temperature
2. High temperature and low pressure
3. High pressure and low temperature
4. High temperature and high pressure
The solubility of BaSO4 in water is g/ litre at 298 K. The value of the solubility product will be: (Molar mass of BaSO4 = 233 gmol–1)
1. | 1.08 × 10–10 mol2 L–2 | 2. | 1.08 × 10–12 mol2 L–2 |
3. | 1.08 × 10–14 mol2 L–2 | 4. | 1.08 × 10–8 mol2 L–2 |
A Lewis base among the following is:
1. | BF3 | 2. | PF3 |
3. | CF4 | 4. | SiF4 |
The concentration of ion in a solution containing 0.1 M HCN and 0.2 M NaCN will be:
( for HCN = )
1. 3.1
2.
3.
4.
The addition of HCl does not suppress the ionization of:
1. | Acetic acid | 2. | Benzoic acid |
3. | H2S | 4. | H2SO4 |