Reaction quotient for the reaction, ${\mathrm{N}}_2\left(\mathrm{g}\right)+3{\mathrm{H}}_2\left(\mathrm{g}\right)\rightleftharpoons 2{\mathrm{NH}}_3\left(\mathrm{g}\right)$ is given by , $\mathrm{Q}$ $=$ $\frac{{\left[{\mathrm{NH}}_3\right]}^2}{\left[{\mathrm{N}}_2\right]{\left[{\mathrm{H}}_2\right]}^3}$ .The reaction will proceed from right to left if K_c value is:

1.	Q<Kc	2.	Q=0
3.	Q>Kc	4.	Q=Kc

An acid buffer solution can be prepared by mixing the solutions of:

1. Sodium chloride and sodium hydroxide

2. Sulphuric acid and sodium sulphate

3. Ammonium chloride and ammonium nitrate

4. Ammonium acetate and acetic acid

The basic buffer solution among the following is: 

1. ${\mathrm{NH}}_4\mathrm{Cl}+{\mathrm{NH}}_4\mathrm{OH}$

2. $\mathrm{NaCl}+\mathrm{NaOH}$

3. ${\mathrm{NH}}_4\mathrm{Cl}+{\mathrm{CH}}_3\mathrm{COOH}$

4. ${\mathrm{CH}}_3\mathrm{COONa}+{\mathrm{CH}}_3\mathrm{COOH}$

The pK_a of HCN is 9.30. The pH of a solution prepared by mixing 2.5 moles of KCN and 2.5 moles of HCN in water and making up the total volume to 500 ml will be:

The pH of a solution made by mixing 50 mL of 0.01 M barium hydroxide solution with 50 mL of H₂O is

When NH₄Cl is added to an aqueous solution of NH₄OH, then

1. Concentration of $\left[{\mathrm{OH}}^{-}\right]$ ions decreases.

2. Concentration of $\left[{\mathrm{OH}}^{-}\right]$ ions increases.

3. Concentration of $\left[{\mathrm{NH}}_4^{+}\right]$ ions as well as concentration $\left[{\mathrm{OH}}^{-}\right]$ ions increase.

4. Concentration of $\left[{\mathrm{NH}}_4^{+}\right]$ ions decreases.

The solubility of $\mathrm{Ni}{\left(\mathrm{OH}\right)}_2$ in 0.1 M NaOH is:

K_sp ($\mathrm{Ni}{\left(\mathrm{OH}\right)}_2$)= 2x ${10}^{-15}$

1. 2 x ${10}^{-8}$ M.

2. 1 x ${10}^{-13}$ M

3. 1 x ${10}^8$ M 

4. 2 x ${10}^{-13}$ 

The K_sp of Ag₂CrO₄ and AgBr is 1.1 × 10^–12 and 5.0 × 10^–13 respectively.

The minimum volume of water required to dissolve 1g of calcium sulphate at 298 K is

(For CaSO₄ , K_sp is 9.1 × 10^–6)

1. 1.22 L

2. 0.69 L

3. 2.44 L

4. 1.87 L

The concentration of $\left[{\mathrm{H}}^{+}\right]$ ion in a solution containing 0.1 M HCN and 0.2 M NaCN will be:

(${\mathrm{K}}_{\mathrm{a}}$ for HCN = $6.2\times {10}^{-10}$)

1. 3.1$\times {10}^{10}$

2. $6.2\times {10}^5$

3.$$ $6.2\times {10}^{-10}$

4. $3.1\times {10}^{-10}$