Assertion (A): |
A five times increase in pressure at equilibrium doesn't change Kp for the following reaction
\(N_2 (g) + 3H_2(g) \rightleftharpoons 2NH_3 (g) \) |
Reason (R): | Kp depends on the degree of dissociation, not on total pressure. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Assertion (A): | A catalyst does not influence the value of the equilibrium constant. |
Reason (R): | The catalyst influences the rate of both forward and backward reactions equally. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
Assertion (A): | For an exothermic reaction, the value of Kc decreases on increasing the temperature. |
Reason (R): | Rate constant for a backward reaction increases more than the increase in the rate constant for a forward reaction. |
1. |
Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Given below are two statements:
Assertion (A): | In the dissociation of PCl5 at constant pressure and temperature, the addition of helium at equilibrium increases the dissociation of PCl5. |
Reason (R): | Helium reacts with Cl2 . |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Assertion (A): | For any chemical reaction at a particular temperature, the equilibrium constant is fixed and is a characteristic property. |
Reason (R): | Equilibrium constant is independent of temperature. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Assertion: At equilibrium,
Reason: When \(K_c> Q_c\), the reaction mainly goes in the forward direction.
1. | Both assertion & reason are true and the reason is the correct explanation of the assertion. |
2. | Both assertion & reason are true but the reason is not the correct explanation of the assertion. |
3. | Assertion is a true statement but the reason is false. |
4. | Both assertion and reason are false statements. |
Assertion: The equilibrium constant of a reaction changes by changing the stoichiometric coefficients of the reaction.
Reason: The reaction,
and have the same equilibrium constant.
1. Both assertion & reason are true and the reason is the correct explanation of the assertion.
2. Both assertion & reason are true but the reason is not the correct explanation of the assertion.
3. Assertion is a true statement but the reason is false.
4. Both assertion and reason are false statements.
Assertion (A): | For a reaction, the concentration quotient (Q) is equal to K when the reaction is in equilibrium. |
Reason (R): | If a catalyst is added to the reaction at equilibrium, the value of Q remains unchanged and is no longer equal to K. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
Assertion (A): | The reaction for which ∆n=0 there is no effect of pressure on equilibrium. |
Reason (R): | A change in pressure results in no change in the value of the equilibrium constant. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
Assertion (A): | A catalyst does not influence the values of the equilibrium constant. |
Reason (R): | The catalyst affects the rate of both forward and reverse reactions equally. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |