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Q. No.In which of the following equilibria, \(\text{K}_\text{p}\) and \(\text{K}_\text{c}\) are NOT equal?
1. \(\mathrm{H}_{2(\mathrm{~g})}+\mathrm{I}_{2(\mathrm{~g})} \rightleftharpoons 2 \mathrm{HI}_{(\mathrm{g})}\)
2. \(\mathrm{CO}_{(\mathrm{g})}+\mathrm{H}_2 \mathrm{O}_{(\mathrm{g})} \rightleftharpoons \mathrm{CO}_{2(\mathrm{~g})}+\mathrm{H}_{2(\mathrm{~g})}\)
3. \(2 \mathrm{BrCl}_{(\mathrm{g})} \rightleftharpoons \mathrm{Br}_{2(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{~g})}\)
4. \(\mathrm{PCl}_{5(\mathrm{~g})} \rightleftharpoons \mathrm{PCl}_{3(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{~g})}\)
Subtopic: Kp, Kc & Factors Affecting them |
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NEET - 2024
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Consider the following reaction in a sealed vessel at equilibrium with concentrations of
\(\text{N}_2=3.0 \times 10^{-3} \text{M}, \text{O}_2=4.2 \times 10^{-3} \text{M}\) and
\(\text{NO}=2.8 \times 10^{-3}\)
\(2 \text{NO}_{(\text{g})} \rightleftharpoons \text{N}_{2(\text{g})} +\text{O}_{2\text{(g)}}\)
If 0.1 mol L-1 of NO(g) is taken in a closed vessel, what will be degree of dissociation (\(\alpha\)) of NO(g) at equilibrium?
1. 0.0889
2. 0.8889
3. 0.717
4. 0.00889
\(\text{N}_2=3.0 \times 10^{-3} \text{M}, \text{O}_2=4.2 \times 10^{-3} \text{M}\) and
\(\text{NO}=2.8 \times 10^{-3}\)
\(2 \text{NO}_{(\text{g})} \rightleftharpoons \text{N}_{2(\text{g})} +\text{O}_{2\text{(g)}}\)
If 0.1 mol L-1 of NO(g) is taken in a closed vessel, what will be degree of dissociation (\(\alpha\)) of NO(g) at equilibrium?
1. 0.0889
2. 0.8889
3. 0.717
4. 0.00889
Subtopic: Ionisation Constant of Acid, Base & Salt |
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Consider the reaction in equilibrium
\(\mathrm{PCl}_5=\mathrm{PCl}_3+\mathrm{Cl}_2\)
at \(500 \mathrm{~K} .\) The concentration of \(\mathrm{PCl}_5=1.40~ \mathrm{M} \text {, }\) concentration of \(\mathrm{Cl}_2=1.60~ \mathrm{M} \text {, }\) concentration of \(\mathrm{PCl}_3=1.60 \mathrm{M}\). Calculate \(K_c\):
1. 2.00
2. 2.6
3. 1.83
4. 3.4
\(\mathrm{PCl}_5=\mathrm{PCl}_3+\mathrm{Cl}_2\)
at \(500 \mathrm{~K} .\) The concentration of \(\mathrm{PCl}_5=1.40~ \mathrm{M} \text {, }\) concentration of \(\mathrm{Cl}_2=1.60~ \mathrm{M} \text {, }\) concentration of \(\mathrm{PCl}_3=1.60 \mathrm{M}\). Calculate \(K_c\):
1. 2.00
2. 2.6
3. 1.83
4. 3.4
Subtopic: Kp, Kc & Factors Affecting them |
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For the equilibrium
\(\mathrm{2NOCl_\text{(g)}\rightleftharpoons2NO_{\text{(g)}}+Cl_{2{\text{(g)}}}}\)
the value of the equilibrium constant is \(3.0\times10^{-6} \) at \(1000~K.\) Find \(K_p\) for the reaction at this temperature (Given \(R:8.314~\text{J K}^{-1}\text{mol}^{-1}\)):
1. \(1.493\)
2. \(2.494\times10^{-2}\)
3. \(3.0\times10^{-6}\)
4. \(2.494\times10^{-4}\)
\(\mathrm{2NOCl_\text{(g)}\rightleftharpoons2NO_{\text{(g)}}+Cl_{2{\text{(g)}}}}\)
the value of the equilibrium constant is \(3.0\times10^{-6} \) at \(1000~K.\) Find \(K_p\) for the reaction at this temperature (Given \(R:8.314~\text{J K}^{-1}\text{mol}^{-1}\)):
1. \(1.493\)
2. \(2.494\times10^{-2}\)
3. \(3.0\times10^{-6}\)
4. \(2.494\times10^{-4}\)
Subtopic: Kp, Kc & Factors Affecting them |
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For the reaction \(2 \mathrm{~A} \rightleftharpoons \mathrm{B}+\mathrm{C}, \mathrm{K}_{\mathrm{c}}=4 \times 10^{-3}\) . At a given time, the composition of reaction mixture is : \([\mathrm{A}]=[\mathrm{B}]=[\mathrm{G}]=2 \times 10^{-3} \mathrm{M} \text {. }\)
Then, which of the following is correct?
1. Reaction has a tendency to go in forward direction.
2. Reaction has a tendency to go in backward direction.
3. Reaction has gone to completion in forward direction.
4. Reaction is at equilibrium.
Then, which of the following is correct?
1. Reaction has a tendency to go in forward direction.
2. Reaction has a tendency to go in backward direction.
3. Reaction has gone to completion in forward direction.
4. Reaction is at equilibrium.
Subtopic: Introduction To Equilibrium |
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At a given temperature and pressure, the equilibrium constant value for the equilibria are given below:
\(3A_2+B_2\rightleftharpoons 2A_3B, K_1\\ A_3B \rightleftharpoons \frac 3{2}A_2+\frac 1{2}B_2, K_2 \)
The relation between \(K_1\) and \(K_2\) is:
1. \(K^2_1=2K_2\)
2. \(K_2= \frac { K_1 }{2}\)
3. \(K_1=\frac 1{\sqrt K_2}\)
4. \(K_2=\frac 1{\sqrt K_1}\)
\(3A_2+B_2\rightleftharpoons 2A_3B, K_1\\ A_3B \rightleftharpoons \frac 3{2}A_2+\frac 1{2}B_2, K_2 \)
The relation between \(K_1\) and \(K_2\) is:
1. \(K^2_1=2K_2\)
2. \(K_2= \frac { K_1 }{2}\)
3. \(K_1=\frac 1{\sqrt K_2}\)
4. \(K_2=\frac 1{\sqrt K_1}\)
Subtopic: Introduction To Equilibrium |
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For the reaction in equilibrium
\(\mathrm{N_2(g) +3H_2(g) \rightleftharpoons 2NH_3(g), \Delta H=-Q}\)
Reaction is favoured in forward direction by:
\(\mathrm{N_2(g) +3H_2(g) \rightleftharpoons 2NH_3(g), \Delta H=-Q}\)
Reaction is favoured in forward direction by:
| 1. | Use of catalyst |
| 2. | Decreasing concentration of \(\mathrm{N_2}\) |
| 3. | Low pressure, high temperature and high concentration of ammonia |
| 4. | High pressure, low temperature and higher concentration of \(\mathrm{H_2}\) |
Subtopic: Le Chatelier's principle |
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The ratio of solubility of \(\mathrm{AgCl}\) in \(0.1~ \mathrm{M} ~\mathrm{KCl}\) solution to the solubility of \( \mathrm{Ag} \mathrm{Cl}\) in water is:
(Given : Solubility product of \(\mathrm{AgCl}=10^{-10}\) )
1. \(10^{-4}\)
2. \(10^{-6}\)
3. \(10^{-9}\)
4. \(10^{-5}\)
(Given : Solubility product of \(\mathrm{AgCl}=10^{-10}\) )
1. \(10^{-4}\)
2. \(10^{-6}\)
3. \(10^{-9}\)
4. \(10^{-5}\)
Subtopic: Solubility Product |
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For a weak acid HA, the percentage of dissociation is nearly 1% at equilibrium. If the concentration of acid is 0.1 mol L-1, then the correct option for its Ka at the same temperature will be:
| 1. | \(1 \times 10^{-4}\) |
| 2. | \(1 \times 10^{-6} \) |
| 3. | \(1 \times 10^{-5} \) |
| 4. | \(1 \times 10^{-3} \) |
Subtopic: Ionisation Constant of Acid, Base & Salt |
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Which combination of the following substances will result in the formation of an acidic buffer when mixed?
| 1. | Weak acid and it's salt with a strong base. |
| 2. | Equal volumes of equimolar solutions of weak acid and weak base. |
| 3. | Strong acid and its salt with a strong base. |
| 4. | Strong acid and its salt with a weak base. (The pKa of acid = pKb of the base) |
Subtopic: Buffer |
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