In the reaction A(g) + 2B(g) ⇌ 2C(g) + D(g), the initial concentration of B is twice that of A and, at equilibrium, the concentrations of A and D are equal. The value of the equilibrium constant will be:

1.	4	2.	16
3.	2	4.	1

The degree of hydrolysis of the salt is independent of the concentration of a solution: 
1. NH₄CI
2. NH₄CN
3. (NH₄)₂SO₄
4. All of the above

The dissociation of solid ${\mathrm{NH}}_4\mathrm{SH}$ in a closed container produces a pressure of 4 atm at $95°\mathrm{C}$, then ${\mathrm{K}}_{\mathrm{p}}$ for the reaction will be:

${\mathrm{NH}}_4\mathrm{SH}\left(\mathrm{s}\right)\stackrel{}{\rightleftharpoons }{\mathrm{NH}}_3\left(\mathrm{g}\right)+{\mathrm{H}}_2\mathrm{S}\left(\mathrm{g}\right)$

The number of ${\mathrm{H}}^{\oplus }$ ions present in 1 ml of a solution whose pH= 4 , is given as:

($N_A=$ $Avogadro\text{'}s$ $number$)

1. ${10}^{-7}{N}_A$

2. ${10}^{-8}{N}_A$

3. ${10}^{-16}{N}_A$

4. ${10}^{-14}{N}_A$

If the pH of an acidic buffer is 5.7 and ${\mathrm{pK}}_{\mathrm{a}}$ is 5 then the ratio of $\frac{\left[\mathrm{Salt}\right]}{\left[\mathrm{Acid}\right]}$ will be:

On adding NH₄CI to an NH₄OH solution, the pH of the solution will

Assertion: The equilibrium constant of a reaction changes by changing the stoichiometric coefficients of the reaction.

Reason: The reaction, $2N{O}_2\left(g\right)\underset{}{\rightleftharpoons }{N}_2{O}_4\left(g\right)$

and $N{O}_2\left(g\right)\underset{}{\rightleftharpoons }\frac{1}{2}{N}_2{O}_4\left(g\right)$ have the same equilibrium constant.

1. Both assertion & reason are true and the reason is the correct explanation of the assertion.

2. Both assertion & reason are true but the reason is not the correct explanation of the assertion.

3. Assertion is a true statement but the reason is false.

4. Both assertion and reason are false statements.