The IUPAC name of [\(\mathrm {C r \left(en\right)_{3}}\)]\(\mathrm{C l}_{3}\) is:
1. | Triethylenediaminechromium (III) chloride |
2. | Tris(ethylenediammine)chromium (II) chloride |
3. | Tris(ethylenediammine)chromium (III) chloride |
4. | Tris(ethylenediamine)chromium (II) chloride |
The crystal field stabilization energy (CFSE) for [CoCl6]4– is 18000 cm–1.
The CFSE for [CoCl4]2– will be:
1.
2.
3.
4.
The electronic configuration that represents the maximum magnetic moment is:
1.
2.
3.
4. (high spin)
Spin-only magnetic moments of [Fe(NH3)6]3+ and [FeF6]3- in BM are, respectively :
1. | 1.73 and 1.73 | 2. | 5.92 and 1.73 |
3. | 1.73 and 5.92 | 4. | 5.92 and 5.92 |
2.335 g of compound X (empirical formal CoH12N4Cl3) upon treatment with excess AgNO3 solution produces 1.435 g of a white precipitate. The primary and secondary valences of cobalt in compound X, respectively are:
[Given Atomic mass: Co = 59, Cl = 35.5, Ag = 108]
1. | 3, 6 | 2. | 3, 4 |
3. | 2, 4 | 4. | 4, 3 |
The expected number of unpaired electrons for the complex ion [Cr(NH3)6]3+ are:
1. 2
2. 3
3. 4
4. 5
The complex that contains only one unpaired electron is:
1. [CoF6]3-
2. [Co(C2O4)3]3-
3. [Fe(CN)6]3-
4. [MnCl6]3-
The complex that can exhibit linkage isomerism is:
1. | [Co(NH3)5H2O]Cl3 | 2. | [Co(NH3)5(NO2)]Cl2 |
3. | [Co(NH3)5NO3](NO3)2 | 4. | [CO(NH3)5Cl]SO4 |
The low spin complex among the following is:
1. | \(\mathrm{Fe}(\mathrm{CN})_6^{3-} \) | 2. | \(\mathrm{Co}\left(\mathrm{NO}_2\right)_6^{3-} \) |
3. | \(\mathrm{Mn}(\mathrm{CN})_6^{3-} \) | 4. | All of the above |
For a tetrahedral complex [MCl4]2-, the spin-only magnetic moment is 3.83 B.M. The element M is:
1. Co
2. Cu
3. Mn
4. Fe