Q. No.Which of the following are paramagnetic?
Choose the correct answer from the options given below:
1. A and D only
2. A, D and E only
3. A and C only
4. B and E only
| A. | \(\left[{NiCl}_4\right]^{2-}\) |
| B. | \(Ni(CO)_4\) |
| C. | \(\left[{Ni}({CN})_4\right]^{2-}\) |
| D. | \(\left[{Ni}\left({H}_2 {O}\right)_6\right]^{2+}\) |
| E. | \({Ni}\left({PPh}_3\right)_4\) |
Choose the correct answer from the options given below:
1. A and D only
2. A, D and E only
3. A and C only
4. B and E only
Subtopic: VBT, CFT & their Limitations |
From NCERT
NEET - 2025
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The correct order of the wavelength of light absorbed by the following complexes is.
Choose the correct answer from the options given below:
1. \(C<D<A<B\)
2. \(C<A<D<B\)
3. \(B<D<A<C\)
4. \(B<A<D<C\)
| A. | \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+} \) | B. | \(\left[\mathrm{Co}(\mathrm{CN})_6\right]^{3-} \) |
| C. | \(\left[\mathrm{Cu}\left(\mathrm{H}_2 \mathrm{O}\right)_4\right]^{2+} \) | D. | \(\left[\mathrm{Ti}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}\) |
Choose the correct answer from the options given below:
1. \(C<D<A<B\)
2. \(C<A<D<B\)
3. \(B<D<A<C\)
4. \(B<A<D<C\)
Subtopic: VBT, CFT & their Limitations |
54%
From NCERT
NEET - 2025
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Given below are two statements :
In the light of the above statements, choose the correct answer from the options given below:
1. Both Statement I and Statement II are False.
2. Statement I is True and Statement II is False.
3. Statement I is False but Statement II is True.
4. Both Statement I and Statement II are True.
| Statement I : | Both \(\left[\text{Co}\left(\text{NH}_3\right)_6\right]^{3+}\) and \(\left[\text{CoF}_6\right]^{3-}\) Complexes are octahedral but differ in their magnetic behaviour. |
| Statement II : | \(\left[\text{Co}\left(\text{NH}_3\right)_6\right]^{3+}\) is diamagnetic whereas \(\left[\text{CoF}_6\right]^{3-}\) is paramagnetic. |
1. Both Statement I and Statement II are False.
2. Statement I is True and Statement II is False.
3. Statement I is False but Statement II is True.
4. Both Statement I and Statement II are True.
Subtopic: VBT, CFT & their Limitations |
73%
From NCERT
NEET - 2024
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NEET 2026 - Target Batch - Vital
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The correct 'spin only' magnetic moments of \([\text{CoF}_6]^{3-}\) and \(\left[\mathrm{Co}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}\) respectively, are:
1. 0 BM and 4.9 BM
2. 0 BM and 0 BM
3. 4.9 BM and 0 BM
4. 4.9 BM and 4.9 BM
1. 0 BM and 4.9 BM
2. 0 BM and 0 BM
3. 4.9 BM and 0 BM
4. 4.9 BM and 4.9 BM
Subtopic: VBT, CFT & their Limitations |
72%
From NCERT
NEET - 2024
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NEET 2026 - Target Batch - Vital
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NEET 2026 - Target Batch - Vital
Match the complex ions in List-I with their corresponding hybridization in List-II.
Choose the correct answer from the options given below:
1. A-IV, B-III, C-II, D-I
2. A-III, B-I, C-IV, D-II
3. A-I, B-II, C-III, D-IV
4. A-III, B-IV, C-II, D-I
| List -I (Complex ion) |
List -II (Hybridisation) |
||
| A. | \([\mathrm{Ni}(\mathrm{CN})_4]^{2-}\) | I. | \(s p^3 \) |
| B. | \(\mathrm{[CoF_6}]^{3-}\) | II. | \( d^2sp^3 \) |
| C. | \([\mathrm{Co}(\mathrm{C}_2 \mathrm{O}_4)_3 ]^{3-}\) | III. | \(s p^3d^2\) |
| D. | \(\mathrm{[NiCl_4}]^{2-}\) | IV. | \(dsp^2\) |
Choose the correct answer from the options given below:
1. A-IV, B-III, C-II, D-I
2. A-III, B-I, C-IV, D-II
3. A-I, B-II, C-III, D-IV
4. A-III, B-IV, C-II, D-I
Subtopic: VBT, CFT & their Limitations |
84%
From NCERT
NEET - 2024
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The crystal field stabilisation energy (CFSE) and the 'spin only' magnetic moment of \(\mathrm{[FeF_6]^{3-}}\) ion respectively, are:
1. \(0~\Delta~\text{and}~5.9~\text{BM}\)
2. \(0~\Delta~\text{and}~1.73~\text{BM}\)
3. \(2.0~\Delta~\text{and}~5.9~\text{BM}\)
4. \(2.0~\Delta~\text{and}~1.73~\text{BM}\)
1. \(0~\Delta~\text{and}~5.9~\text{BM}\)
2. \(0~\Delta~\text{and}~1.73~\text{BM}\)
3. \(2.0~\Delta~\text{and}~5.9~\text{BM}\)
4. \(2.0~\Delta~\text{and}~1.73~\text{BM}\)
Subtopic: VBT, CFT & their Limitations |
69%
From NCERT
NEET - 2024
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The order of energy absorbed which is responsible for the color of complexes is:
\((A) \ \left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2}(\text { en })_{2}\right]^{2+}\)
\( (B) \ \left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4}(\mathrm{en})\right]^{2+} and\)\( (C) \ \left[\mathrm{Ni}(\mathrm{en})_{3}\right]^{2+}\)
\((A) \ \left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2}(\text { en })_{2}\right]^{2+}\)
\( (B) \ \left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4}(\mathrm{en})\right]^{2+} and\)\( (C) \ \left[\mathrm{Ni}(\mathrm{en})_{3}\right]^{2+}\)
| 1. | B > A > C | 2. | A > B > C |
| 3. | C > B > A | 4. | C > A > B |
Subtopic: VBT, CFT & their Limitations |
65%
From NCERT
NEET - 2022
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NEET 2026 - Target Batch - Vital
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NEET 2026 - Target Batch - Vital
The correct order of spin-only magnetic moment for the given complexes is:
1. \([Co(H_2O)_6]^{2+} > [MnCl_6]^{3-} > [Fe(CN)_6]^{3-} \)
2. \([Fe(CN)_6]^{3-} >[Co(H_2O)_6]^{2+} > [MnCl_6]^{3-} \)
3. \([MnCl_6]^{3-} >[Fe(CN)_6]^{3-} >[Co(H_2O)_6]^{2+} \)
4. \([MnCl_6]^{3-} > [Co(H_2O_6]^{2+} > [Fe(CN)_6]^{3-} \)
Subtopic: VBT, CFT & their Limitations |
63%
From NCERT
NEET - 2022
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NEET 2026 - Target Batch - Vital
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NEET 2026 - Target Batch - Vital
Match Column I with Column II, Columns I and II represent complexes and magnetic moment (BM) respectively.
| Column I | Column II |
| (a) [FeCN6]3- | (i) 5.92 BM |
| (b) [Fe(H2O)6]3+ | (ii) 0 BM |
| (c) [Fe(CN)6]4- | (iii) 4.90 BM |
| (d) [Fe(H2O)6]2+ | (iv) 1.73 BM |
Choose the correct answer from the options given below:
| (a) | (b) | (c) | (d) | |
| 1. | (i) | (iii) | (iv) | (ii) |
| 2. | (iv) | (i) | (ii) | (iii) |
| 3. | (iv) | (ii) | (i) | (iii) |
| 4. | (ii) | (iv) | (iii) | (i) |
Subtopic: VBT, CFT & their Limitations |
69%
From NCERT
NEET - 2021
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NEET 2026 - Target Batch - Vital
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NEET 2026 - Target Batch - Vital
What is the correct electronic configuration of the central atom in \(K_{4}FeCN_{6}\) based on crystal field theory:
1. \(e^{4} t_{2 g}^{ 2}\)
2. \(t_{2 g}^{ 4} e_{g}^{2}\)
3. \(t_{2 g}^{ 6} e_{g}^{0}\)
4. \(e^{3} t_{2 g}^{ 3}\)
Subtopic: VBT, CFT & their Limitations |
81%
From NCERT
NEET - 2019
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NEET 2026 - Target Batch - Vital
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NEET 2026 - Target Batch - Vital
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