Which of the following are paramagnetic? 
A. \(\left[{NiCl}_4\right]^{2-}\)
B. \(Ni(CO)_4\)
C. \(\left[{Ni}({CN})_4\right]^{2-}\)
D. \(\left[{Ni}\left({H}_2 {O}\right)_6\right]^{2+}\)
E. \({Ni}\left({PPh}_3\right)_4\)

Choose the correct answer from the options given below: 
1. A and D only 
2. A, D and E only 
3. A and C only 
4. B and E only 
Subtopic:  VBT, CFT & their Limitations |
From NCERT
NEET - 2025
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The correct order of the wavelength of light absorbed by the following complexes is. 
A. \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+} \) B. \(\left[\mathrm{Co}(\mathrm{CN})_6\right]^{3-} \)
C. \(\left[\mathrm{Cu}\left(\mathrm{H}_2 \mathrm{O}\right)_4\right]^{2+} \) D. \(\left[\mathrm{Ti}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}\)

Choose the correct answer from the options given below: 
1. \(C<D<A<B\)
2. \(C<A<D<B\)
3. \(B<D<A<C\)
4. \(B<A<D<C\)
Subtopic:  VBT, CFT & their Limitations |
 56%
From NCERT
NEET - 2025
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Given below are two statements :
Statement I : Both \(\left[\text{Co}\left(\text{NH}_3\right)_6\right]^{3+}\) and \(\left[\text{CoF}_6\right]^{3-}\) Complexes are octahedral but differ in their magnetic behaviour.
Statement II : \(\left[\text{Co}\left(\text{NH}_3\right)_6\right]^{3+}\) is diamagnetic whereas \(\left[\text{CoF}_6\right]^{3-}\) is paramagnetic.
In the light of the above statements, choose the correct answer from the options given below:
1. Both Statement I and Statement II are False.
2. Statement I is True and Statement II is False.
3. Statement I is False but Statement II is True.
4. Both Statement I and Statement II are True.
Subtopic:  VBT, CFT & their Limitations |
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From NCERT
NEET - 2024
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The correct 'spin only' magnetic moments of \([\text{CoF}_6]^{3-}\) and \(\left[\mathrm{Co}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}\) respectively, are:
1. 0 BM and 4.9 BM
2. 0 BM and 0 BM
3. 4.9 BM and 0 BM
4. 4.9 BM and 4.9 BM
Subtopic:  VBT, CFT & their Limitations |
 72%
From NCERT
NEET - 2024
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Match the complex ions in List-I with their corresponding hybridization in List-II.
List -I
(Complex ion)
List -II
(Hybridisation)
A.  \([\mathrm{Ni}(\mathrm{CN})_4]^{2-}\) I.  \(s p^3 \)
B.  \(\mathrm{[CoF_6}]^{3-}\) II.  \( d^2sp^3 \)
C.  \([\mathrm{Co}(\mathrm{C}_2 \mathrm{O}_4)_3 ]^{3-}\) III.  \(s p^3d^2\)
D.  \(\mathrm{[NiCl_4}]^{2-}\) IV.  \(dsp^2\)

Choose the correct answer from the options given below:
1. A-IV, B-III, C-II, D-I
2. A-III, B-I, C-IV, D-II
3. A-I, B-II, C-III, D-IV
4. A-III, B-IV, C-II, D-I
Subtopic:  VBT, CFT & their Limitations |
 84%
From NCERT
NEET - 2024
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The crystal field stabilisation energy (CFSE) and the 'spin only' magnetic moment of \(\mathrm{[FeF_6]^{3-}}\) ion respectively, are:

1. \(0~\Delta~\text{and}~5.9~\text{BM}\)
2. \(0~\Delta~\text{and}~1.73~\text{BM}\)
3. \(2.0~\Delta~\text{and}~5.9~\text{BM}\)
4. \(2.0~\Delta~\text{and}~1.73~\text{BM}\)
Subtopic:  VBT, CFT & their Limitations |
 69%
From NCERT
NEET - 2024
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The order of energy absorbed which is responsible for the color of complexes is:
\((A) \ \left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2}(\text { en })_{2}\right]^{2+}\)
\( (B) \ \left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4}(\mathrm{en})\right]^{2+} and\)\( (C) \ \left[\mathrm{Ni}(\mathrm{en})_{3}\right]^{2+}\)
1. B > A > C  2. A > B > C 
3. C > B > A  4. C > A > B
Subtopic:  VBT, CFT & their Limitations |
 65%
From NCERT
NEET - 2022
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The correct order of spin-only magnetic moment for the given complexes is: 

1. \([Co(H_2O)_6]^{2+} > [MnCl_6]^{3-} > [Fe(CN)_6]^{3-} \)
2. \([Fe(CN)_6]^{3-} >[Co(H_2O)_6]^{2+} > [MnCl_6]^{3-} \)
3. \([MnCl_6]^{3-} >[Fe(CN)_6]^{3-} >[Co(H_2O)_6]^{2+} \)
4. \([MnCl_6]^{3-} > [Co(H_2O_6]^{2+} > [Fe(CN)_6]^{3-} \)

Subtopic:  VBT, CFT & their Limitations |
 63%
From NCERT
NEET - 2022
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Match Column I with Column II, Columns I and II represent complexes and magnetic moment (BM) respectively. 

Column I Column II
(a) [FeCN6]3- (i) 5.92 BM
(b) [Fe(H2O)6]3+ (ii) 0 BM
(c) [Fe(CN)6]4- (iii) 4.90 BM
(d) [Fe(H2O)6]2+ (iv) 1.73 BM

Choose the correct answer from the options given below:

(a) (b) (c) (d)
1. (i) (iii) (iv) (ii)
2. (iv) (i) (ii) (iii)
3. (iv) (ii) (i) (iii)
4. (ii) (iv) (iii) (i)
Subtopic:  VBT, CFT & their Limitations |
 69%
From NCERT
NEET - 2021
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What is the correct electronic configuration of the central atom in \(K_{4}FeCN_{6}\) based on crystal field theory:

1. \(e^{4}   t_{2 g}^{    2}\)

2. \(t_{2 g}^{    4}   e_{g}^{2}\)

3. \(t_{2 g}^{    6}   e_{g}^{0}\)

4. \(e^{3}   t_{2 g}^{  3}\)

Subtopic:  VBT, CFT & their Limitations |
 81%
From NCERT
NEET - 2019
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