Statement I: | \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}\) is a homoleptic complex, whereas \([Co(NH_3)_4 Cl_2]^+\) is a heteroleptic complex. |
Statement II: | Complex \([Co(NH_3)_6]^{3+}\) has only one kind of ligands but \([Co(NH_3)_4 Cl_2]^+\) has more than one kind of ligand |
The correct order of the stoichiometries of AgCl formed when AgNO3 in excess is treated with the complexes
CoCl3.6NH3, CoCl3.5NH3, CoCl3.4NH3 respectively is:
1. 3AgCl, 1AgCl, 2AgCl
2. 3AgCl, 2AgCl, 1AgCl
3. 2AgCl, 3AgCl, 1AgCl
4. 1AgCl, 3AgCl, 2AgCl
The sum of the coordination number and oxidation number of the metal M in the complex [M(en)2(C2O4)]Cl is:
1. | 9 | 2. | 6 |
3. | 7 | 4. | 8 |
The IUPAC name of complex ion, [Fe(CN)6]3- is:
1. Hexacyanoiron(III) ion
2. Hexacyanitoferrate(III) ion
3. Tricynoferrate(III) ion
4. Hexacyanidoferrate(III) ion
Cobalt(III) chloride forms several octahedral complexes with ammonia.
A compound among the following that does not give a test for chloride ions with silver nitrate at 25 °C is:
1. | CoCl3. 3NH3 | 2. | CoCl3. 4NH3 |
3. | CoCl3. 5NH3 | 4. | CoCl3. 6NH3 |
A complex ion among the following can absorb visible light is:
(At. no. Zn = 30, Sc = 21, Ti = 22, Cr = 24)
1. [Sc(H2O)3(NH3)3]3+
2. [Ti(en)2 (NH3)2]4+
3. [Cr(NH3)6]3+
4. [Zn(NH3)6]2+
Out of , , Cu2Cl2 and (Z of Ti = 22, Co=27, Cu = 29, Ni= 28) the colourless species are:
1.
2.
3.
4.