Indicate the complex ion that shows geometrical isomerism:
1. [Cr(H2O)4 Cl2]+
2. [Pt(NH3)3 Cl]
3. [Co(NH3)6]3+
4. [Co(CN)6]3-
Due to the presence of ambidentate ligands coordination compounds show isomerism. Palladium complexes of the type and are:
1. Linkage isomers
2. Coordination isomers
3. Ionization isomers
4. Geometrical isomers
The compounds [Co(SO (NH) ]Br and [Co(SO (NH)] Cl classified as:
1. | Linkage isomerism | 2. | Ionisation isomerism |
3. | Coordination isomerism | 4. | No isomerism |
What kind of isomerism exists between [Cr(H2O)6]Cl3 (violet) and [Cr(H2O)5Cl]Cl2⋅H2O (greyish-green)?
1. Linkage isomerism
2. Solvate isomerism
3. lonisation isomerism
4. Coordination isomerism
Identify the correct statements for the behaviour of ethane -1, 2- diamine as a ligand.
(a) It is a neutral ligand
(b) It is a didentate ligand
(c) It is a chelating ligand
(d) It is a unidentate ligand
Choose the correct option
1. (a, b, c)
2. (b, c, d)
3. (a, c, d)
4. (a, b, d)
Which of the following complexes show linkage isomerism?
(a)
(b)
(c)
(d)
Choose the correct option
1. (a, b)
2. (b, c)
3. (c, d)
4. (a, c)
Match the complex species given in Column I with the possible isomerism given in Column II and assign the correct code.
Column I (Complex species) |
Column II (Isomerism) |
A. |
1. Optical isomerism |
B. |
2. lonisation Isomerism |
C. |
3. Coordination Isomerism |
D. |
4. Geometrical Isomerism |
Codes:
A B C D
1. 2 3 4 1
2. 3 1 5 2
3. 5 4 3 2
4. 4 1 2 3
Given below are two statements:
Assertion (A): | Linkage isomerism arises in coordination compounds containing ambidentate ligand. |
Reason (R): | Ambidentate ligand has two different donor atoms. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Given below are two statements:
Assertion (A): | Complexes of the types MX6 and MX5L (where X and L represent unidentate ligands) do not exhibit geometrical isomerism. |
Reason (R): | Complexes with a coordination number of 6 do not display geometrical isomerism. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |