[Cr(NH3)6]3+ is paramagnetic ,while is diamagnetic because:
1. | Electrons in the 3d orbitals remain unpaired in |
2. | Electrons in the 3d orbitals remain unpaired in [Cr(NH3)6]3+ |
3. | Electrons in the 3p orbitals remain unpaired in [Cr(NH3)6]3+ |
4. | Electrons in the 3p orbitals remain unpaired in |
The correct electronic configuration of the central atom in based on crystal field theory is:
1. | \(e^4 ~t_{2 g}^2 \) | 2. | \(t_{2 g}^4 ~e_g^2 \) |
3. | \(t_{2 g}^6 ~e_g^0 \) | 4. | \(e^3 ~t^3_{2g}\) |
Which among the following is a diamagnetic complex?
1.
2.
3.
4.
The correct splitting diagram of d orbitals in an octahedral crystal field is:
1. | 2. | ||
3. | 4. | None of these. |
An example of a sigma bonded organometallic compound is:
1. Ruthenocene
2. Grignard's reagent
3. Ferrocene
4. Cobaltocene
Of the following complex ions, the diamagnetic complex is:
1. [Ni(CN)4]2-
2. [CuCl4]2-
3. [CoF6]3-
4. [NiCl4]2-
The hybridisation of [FeF6]3- is:
1. | sp3d2 | 2. | d2sp3 |
3. | dsp3 | 4. | sp3 |
The electronic configuration that represents the maximum magnetic moment is:
1.
2.
3.
4. (high spin)
The low spin complex among the following is:
1. | \(\mathrm{Fe}(\mathrm{CN})_6^{3-} \) | 2. | \(\mathrm{Co}\left(\mathrm{NO}_2\right)_6^{3-} \) |
3. | \(\mathrm{Mn}(\mathrm{CN})_6^{3-} \) | 4. | All of the above |
The hybridisation of Ni in the complex [Ni(CN)4]2- is:
(Atomic number of Ni = 28)
1. dsp2
2. sp3
3. d2sp2
4. d2sp3