Statement I : | Both \(\left[\text{Co}\left(\text{NH}_3\right)_6\right]^{3+}\) and \(\left[\text{CoF}_6\right]^{3-}\) Complexes are octahedral but differ in their magnetic behaviour. |
Statement II : | \(\left[\text{Co}\left(\text{NH}_3\right)_6\right]^{3+}\) is diamagnetic whereas \(\left[\text{CoF}_6\right]^{3-}\) is paramagnetic. |
List -I (Complex ion) |
List -II (Hybridisation) |
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A. | \([\mathrm{Ni}(\mathrm{CN})_4]^{2-}\) | I. | \(s p^3 \) |
B. | \(\mathrm{[CoF_6}]^{3-}\) | II. | \( d^2sp^3 \) |
C. | \([\mathrm{Co}(\mathrm{C}_2 \mathrm{O}_4)_3 ]^{3-}\) | III. | \(s p^3d^2\) |
D. | \(\left(\mathrm{NiCl}_4\right)^{2-}\) | IV. | \(dsp^2\) |
1. | B > A > C | 2. | A > B > C |
3. | C > B > A | 4. | C > A > B |
The correct order of spin-only magnetic moment for the given complexes is:
1. \([Co(H_2O)_6]^{2+} > [MnCl_6]^{3-} > [Fe(CN)_6]^{3-} \)
2. \([Fe(CN)_6]^{3-} >[Co(H_2O)_6]^{2+} > [MnCl_6]^{3-} \)
3. \([MnCl_6]^{3-} >[Fe(CN)_6]^{3-} >[Co(H_2O)_6]^{2+} \)
4. \([MnCl_6]^{3-} > [Co(H_2O_6]^{2+} > [Fe(CN)_6]^{3-} \)
Match Column I with Column II, Columns I and II represent complexes and magnetic moment (BM) respectively.
Column I | Column II |
(a) [FeCN6]3- | (i) 5.92 BM |
(b) [Fe(H2O)6]3+ | (ii) 0 BM |
(c) [Fe(CN)6]4- | (iii) 4.90 BM |
(d) [Fe(H2O)6]2+ | (iv) 1.73 BM |
Choose the correct answer from the options given below:
(a) | (b) | (c) | (d) | |
1. | (i) | (iii) | (iv) | (ii) |
2. | (iv) | (i) | (ii) | (iii) |
3. | (iv) | (ii) | (i) | (iii) |
4. | (ii) | (iv) | (iii) | (i) |
The crystal field stabilization energy (CFSE) for [CoCl6]4– is 18000 cm–1.
The CFSE for [CoCl4]2– will be:
1.
2.
3.
4.
What is the correct electronic configuration of the central atom in based on crystal field theory?
1.
2.
3.
4.