A compound is formed by two elements M and N. The element N forms ccp and atoms of M occupy 1/3rd of tetrahedral voids. The formula of the compound would be -

1. MN

2. M₃N₄

3. M₂N₃

4. M₃N₂

In which of the following crystals are alternate tetrahedral voids occupied:

1. NaCl

2. ZnS

3. CaF₂

4. Na₂O

If 'a’ stands for the edge length of the cubic systems: simple cubic, body-centered cubic, and face-centered cubic, then the ratio of radii of the spheres in these systems will be respectively: 

1. $\frac{1}{2}\mathrm{a\; :}$ $\frac{\sqrt{3}}{4}\mathrm{a}$ $:$ $\frac{1}{{\displaystyle 2}\sqrt{2}}\mathrm{a}$

2. $\frac{1}{2}\mathrm{a\; :}$ $\sqrt{3}\mathrm{a}$ $:$ $\frac{1}{\sqrt{2}}\mathrm{a}$

3. $\frac{1}{2}\mathrm{a\; :}$ $\frac{\sqrt{3}}{2}\mathrm{a}$ $:$ $\frac{\sqrt{2}}{{\displaystyle 2}}\mathrm{a}$

4. $1\mathrm{a\; :}$ $\sqrt{3}\mathrm{a}$ $:$ $\sqrt{2}\mathrm{a}$

Match the type of packing given in Column I with the items given in Column II.

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