The reaction(s) involved in the preparation of potassium dichromate from iron chromite ore is/are:
1. | FeCr2O4 + NaOH + O2 → Na2CrO4 + Fe2O3 + H2O |
2. | Na2CrO4 + H2SO4 (conc.) → Na2Cr2O7 + Na2SO4 + H2O |
3. | Na2Cr2O7 + KCl→ K2Cr2O7 + NaCl |
4. | All of the above. |
The fusion of chromite ore (FeCr2O4) with Na2CO3 in air gives a yellow solution upon the addition of water. Subsequent treatment with H2SO4 produces an orange solution.
The yellow and orange colours, respectively, are due to the formation of:
1. Na2CrO4 and Na2Cr2O7
2. Cr(OH)3 and Na2Cr2O7
3. Cr2(CO3)3 and Fe2(SO4)3
4. Cr(OH)3 and Na2CrO4
When neutral or faintly alkaline is treated with potassium iodide, the iodide ion is converted into 'X'. The formula of 'X' is:
1.
2.
3.
4.
HCl is not used to make the medium acidic in oxidation reaction of , because
1. | Both HCl and KMnO4 act as oxidising agents. |
2. | KMnO4 oxidises HCl into Cl2, which is also an oxidising agent. |
3. | KMnO4 is a weaker oxidising agent than HCl. |
4. | KMnO 4 acts as a reducing agent in the presence of HCl. |
A gas that can readily decolorize an acidified KMnO4 solution is:
1.
2.
3.
4.
CrO42- (yellow) changes to Cr2O72- (orange) in pH = x and vice versa in pH = y.
The value of x and y will be:
1. 6, and 8
2. 6, and 5
3. 8, and 6
4. 7, and 7
Which of the following pairs of substances on reaction will not evolve gas?
1. Iron, and (aq)
2. Iron, and steam
3. Copper, and HCl(g)
4. Sodium, and ethyl alcohol
The oxidation state of chromium in the final product formed by the reaction between KI and acidified potassium dichromate solution will be:
1. +2
2. +3
3. +4
4. +6
Highest oxidation state of manganese in fluoride is +4 (Mn) but the highest oxidation state in oxides is +7 (Mn2O7). The reason is :
1. | Fluorine is more electronegative than oxygen. |
2. | Fluorine does not possess d orbitals. |
3. | Fluorine stabilizes lower oxidation state of Mn. |
4. | In covalent compounds, fluorine can only form a single bond while oxygen forms a double bond. |
When KMnO4 solution is added to hot oxalic acid solution, the decolorization is slow in the beginning but becomes instantaneous after some time. This is because :
1. acts as auto catalyst.
2. is formed.
3. Reaction is exothermic.
4. catalyses the reaction.