| Assertion (A): | p-Toluidine is a stronger base than m-toluidine. |
| Reason (R): | The methyl group from m-position exerts a smaller electron-donating inductive (+l) effect than from p-position. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation for (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation for (A). |
| 3. | (A) is True but (R) is False. |
| 4. | Both (A) and (R) are False. |
| Assertion(A): | Aniline does not undergo Friedel-Crafts reaction. |
| Reason(R) : | Friedel-Crafts is an electrophilic substitution reaction. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | Both (A) and (R) are False. |
| Assertion (A): | Anilinium hydrogen sulphate, on heating, forms meta-aminobenzene sulfonic acid. |
| Reason (R): | The sulfonic acid group is an electron-donating group. |
| 1. | Both (A) and (R) are true, and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
| 3. | (A) is a true statement but (R) is false. |
| 4. | Both (A) and (R) are false statements. |
| Assertion (A): | Anilinium chloride is more acidic than ammonium chloride. |
| Reason (R): | The anilinium ion is resonance-stabilised. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True statement but (R) is False. |
| 4. | Both (A) and (R) are False statements. |
| Assertion (A): | When benzene diazonium chloride is reacted with phenol, then an azo dye is formed. |
| Reason (R): | It is an example of an electrophilic substitution reaction. |
| 1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
| 3. | (A) is a true statement but (R) is false. |
| 4. | Both (A) and (R) are false statements. |
| Assertion (A): | The nucleophiles Cl⁻, Br⁻, and CN⁻ can be easily introduced into the benzene ring of diazonium salts in the presence of Cu(I) ion, a process known as the Sandmeyer reaction. |
| Reason (R): | Aryl fluorides and iodides cannot be prepared by direct halogenation, but they can be easily obtained from diazonium salt |
| 1. | Both (A) and (R) are True, and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True, but (R) is not the correct explanation of (A). |
| 3. | (A) is True, but (R) is False. |
| 4. | (A) is False, but (R) is True. |
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