| Statement I: | Benzenediazonium salt is prepared by the reaction of aniline with nitrous acid at \(273-278~ \text{K}.\) It decomposes easily in the dry state. |
| Statement II: | Insertion of iodine into the benzene ring is difficult, and hence iodobenzene is prepared through the reaction of benzenediazonium salt with \(KI.\) |
| 1. | Statement I is correct; Statement II is incorrect |
| 2. | Statement I is incorrect; Statement II is correct |
| 3. | Both Statement I and Statement II are correct |
| 4. | Both Statement I and Statement II are incorrect |
| Statement I: | Benzendiazonium chloride is a colourless crystalline solid. It is insoluble in water but reacts with water when warmed. |
| Statement II: | Benzendiazonium chloride on reacting with HCI in presence of copper powder gives chlorobenzene as the product. This is an example of Gatterman reaction. |
| 1. | Both Statement I and Statement II is true. |
| 2. | Both Statement I and Statement II is false. |
| 3. | Statement I is true but Statement II is false. |
| 4. | Statement I is false but Statement II is true. |
| 1. | 2. | ||
| 3. | 4. |
| 1. | NaNO2/HCl; Sn/HCl; Br2; H2O/H3PO2 |
| 2. | Sn/HCl; NaNO2/HCl; Br2; H2O/H3PO2 |
| 3. | Br2; Sn/HCl; NaNO2/HCl; H2O/H3PO2 |
| 4. | Sn/HCl; Br2; NaNO2/HCl; H2O/H3PO2 |
| Statement I: | Primary aliphatic amines react with HNO2 to give unstable diazonium salts. |
| Statement II | Primary aromatic amines react with HNO2 to form diazonium salts which are stable even above 300 K. |
| 1. | Statement I is incorrect but Statement II is correct |
| 2. | Both Statement I and II are correct |
| 3. | Both Statement I and II are incorrect |
| 4. | Statement I is correct but Statement II is incorrect |
| 1. | ![]() |
2. | ![]() |
| 3. | ![]() |
4. | ![]() |
The reagent 'R' in the given sequence of a chemical reaction is :
| 1. | HI | 2. | CuCN/KCN |
| 3. | H2O | 4. | CH3CH2OH |
The product (A) in the below-mentioned
reaction is:
| 1. | |
| 2. | |
| 3. | |
| 4. |
The most stable diazonium salt among the following is:
1. \(CH_{3}N_{2}^{+}X^{-}\)
2. \(C_{6}H_{5}N_{2}^{+}X^{-}\)
3. \(CH_{3}CH_{2}N_{2}^{+}X^{-}\)
4. \(C_{6}H_{5}CH_{2}N_{2}^{+}X^{-}\)