Statement I: | Benzendiazonium chloride is a colourless crystalline solid. It is insoluble in water but reacts with water when warmed. |
Statement II: | Benzendiazonium chloride on reacting with HCI in presence of copper powder gives chlorobenzene as the product. This is an example of Gatterman reaction. |
1. | 2. | ||
3. | 4. |
I | Primary aliphatic amines react with HNO2 to give unstable diazonium salts. |
II | Primary aromatic amines react with HNO2 to form diazonium salts which are stable even above 300 K. |
1. | I is incorrect but II is correct |
2. | Both I and II are correct |
3. | Both I and II are incorrect |
4. | I is correct but II is incorrect |
1. | 2. | ||
3. | 4. |
The reagent 'R' in the given sequence of a chemical reaction is :
1. | HI | 2. | CuCN/KCN |
3. | H2O | 4. | CH3CH2OH |
The product (A) in the below-mentioned
reaction is:
1. | 2. | ||
3. | 4. |
The most stable diazonium salt among the following is:
1. \(CH_{3}N_{2}^{+}X^{-}\)
2. \(C_{6}H_{5}N_{2}^{+}X^{-}\)
3. \(CH_{3}CH_{2}N_{2}^{+}X^{-}\)
4. \(C_{6}H_{5}CH_{2}N_{2}^{+}X^{-}\)
An organic compound 'A' on treatment with NH3 gives 'B', which on heating gives 'C'. 'C',
when treated with Br2 in the presence of KOH produces ethylamine. Compound 'A' is:
1. | CH3CH2COOH |
2. | CH3COOH |
3. | CH3CH2CH2COOH |
4. |