For a 1st order reaction following graph is obtained between lnk and \({1000 \over T}\). Then activation energy of reaction in kcal is : 
         

1. 37 kcal
2. 40 kcal
3. 42 kcal
4. 34 kcal
Subtopic:  Arrhenius Equation |
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For a first-order reaction
\(t_{67\%}=\Big(\frac x{10}\Big)t_{50\%}~\&~k=3.84\times10^9~\text{sec}^{-1} \), the value of x will (based on information given):
(Report your answer to the nearest integer)

1. 14 
2. 16 
3. 18 
4. 20
Subtopic:  First Order Reaction Kinetics |
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For the reaction, aA+bBcC+dD the plot of log k vs 1T is given below :

Find the temperature(K) at which the rate constant of the reaction is 10–4s–1 ?

(Rounded-off to the nearest integer) 

[Given: The rate constant of the reaction is 105 s1 at 500 K.] 

1. 546 K 2. 536 K
3. 516 K 4. 526 K
Subtopic:  Arrhenius Equation |
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The rate constant of a reaction increases by five times on increase in temperature from 27°C to 52°C. The value of activation energy in kJ mol–1 is-

(Rounded-off to the nearest integer) [R = 8.314 J K–1 mol–1]

1. 50

2. 56

3. 52

4. 60

Subtopic:  Arrhenius Equation |
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The results given in the below table were obtained during kinetic studies of the following reaction:
2A + B C + D

 Experiment  [A]/mol L-1  [B]/mol L-1  Initial rate/mol L-1 min-1
           I       0.1        0.1  6.00×10-3
          II        0.1        0.2  2.40×10-2
          III        0.2        0.1  1.20×10-2
           IV         X        0.2  7.20×10-2
           V        0.3          Y  2.88×10-1

X and Y in the given table are respectively :

1. 0.3, 0.4

2. 0.4, 0.3

3. 0.4, 0.4

4. 0.3, 0.3

Subtopic:  Order, Molecularity and Mechanism |
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For the reaction 2A + 3B +32C  3P, the correct statement is:

1. dnAdt =23 dnBdt=34dnCdt
2. dnAdt =32 dnBdt=34dnCdt
3. dnAdt = dnBdt=dnCdt
4. dnAdt =23 dnBdt=43dnCdt
Subtopic:  Definition, Rate Constant, Rate Law |
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If 75 % of a first-order reaction was completed in 90 minutes, 60 % of the same reaction would be completed in approximately (in minutes):

(Take : log 2 = 0.30 ; log 2.5 = 0.40)

1. 50 min

2. 60 min

3. 70 min

4. 65 min

Subtopic:  First Order Reaction Kinetics |
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The rate constant (k) of a reaction is measured at different temperatures (T), and the data are plotted in the given figure. The activation energy of the reaction in kJ mol–1 is:
(R is gas constant)

1.  2R
2.  R
3.  1/R
4.  2/R

Subtopic:  Arrhenius Equation |
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The rate of a reaction is decreased by 3.555 times when the temperature was changed from 40°C to 30°C. The activation energy (in kJ mol-1) of the reaction is:
(Take R=8.314 J mol-1 K-1 In 3.555=1.268)

1. 100 kJ/mol
2. 120 kJ/mol
3. 95 kJ/mol
4. 108 kJ/mol

Subtopic:  Arrhenius Equation |
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For the reaction 2A + B C, the values of initial rate at different reactant concentrations are given in the table below. The rate law for the reaction is:

[A] (mol L-1) [B] (mol L-1) Initial Rate (mol L-1 s-1)
0.05 0.05 0.045
0.10 0.05 0.090
0.20 0.10 0.72


1. Rate = k[A] [B]
2. Rate = k [A] [B]2
3. Rate =K [A]2 [B]2
4. Rate = K [A]2 [B]

Subtopic:  Order, Molecularity and Mechanism |
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