In the reaction, both H and S are positive. The condition(s) under which the reaction would not be spontaneous are/is:
1. H>TS
2. S=H/T
3. H=TS
4. All of the above
The values of ΔH and ΔS for the given reaction are 170 kJ and 170 JK-1, respectively.
C(graphite) + CO2(g)→2CO(g)
This reaction will be spontaneous at:
1. 710 K
2. 910 K
3. 1110 K
4. 510 K
Calculate (in kJ/mol) for from the and the values provided at 27C
\(\begin{array}{ll}
4 C r(s)+3 O_2(g) \rightarrow 2 C r_2 O_3(s), \\ \Delta_r G^{\circ}=-2093.4 k J / m o l \\
S^{\circ}(\mathrm{J} / / \mathrm{K} \mathrm{~mol}): S^{\circ}(C r, s)=24, \\ S^{\circ}\left(O_2, g\right)=205, \quad S^{\circ}\left(C r_2 O_3, s\right)=81
\end{array}\)
1. -2258.1 kJ/mol
2. -1129.05 kJ/mol
3. -964.35 kJ/mol
4. None of the above
The free energy change is negative when -
1. The surroundings do no electrical work on the system.
2. The surroundings do electrical work on the system.
3. The system does electrical work on the surroundings.
4. The system does no electrical work on the surroundings.
Equilibrium is represented by:
1. H = 0
2. GTotal = 0
3. STotal = 0
4. E = 0
'The free energy change due to a reaction is zero when-
1. The reactants are initially mixed.
2. A catalyst is added
3. The system is at equilibrium
4. The reactants are completely consumed
For a given reaction, if ΔH = 35.5 kJ/mol and ΔS = 83.6 J/K·mol, at what temperature is the reaction spontaneous?
(Assume ΔH and ΔS remain constant with temperature.)
1. | T < 425 K | 2. | T > 425 K |
3. | All temperatures | 4. | T > 298 K |
The correct statement for a reversible process in a state of equilibrium is:
1. G = – 2.30RT log K
2. G = 2.30RT log K
3. Go = – 2.30RT log K
4. Go = 2.30RT log K
Hydrolysis of sucrose is given by the following reaction
Sucrose + H2O Glucose + Fructose
If the equilibrium constant (Kc) is 21013 at 300 K, the value of at the same temperature will be:
1. 8.314 J mol–1 K–1300 Kln (21013)
2. 8.314 J mol–1 K–1300 Kln (31013)
3. –8.314 J mol–1 K–1300 Kln (41013)
4. –8.314 J mol–1 K–1300 Kln (21013)