When hydrolyzed with aqueous KOH, compounds that undergoes racemization are:
(i) | (ii) | CH3CH2CH2Cl | |
(iii) | (iv) |
1. | (i) and (ii) | 2. | (ii) and (iv) |
3. | (iv) only | 4. | (i) and (iv) |
The end product (C) in the below-mentioned reaction is:
\(H_3C-Br\xrightarrow{\bf KCN }A\xrightarrow{ \bf H_3O^+~~}B\xrightarrow[\bf\text{Ether}]{~~LiAlH_4~~}C\)
Which of the following compounds undergoes nucleophilic substitution reaction most easily?
1. | 2. | ||
3. | 4. |
Consider the reactions:
(i) | \(\small{{(CH_3)}_2CHCH_2Br\ \xrightarrow[]{C_2H_5OH}{(CH_3)}_2CHCH_2OC_2H_5 + HBr}\) |
(ii) | \(\small{{(CH_3)}_2CHCH_2Br\ \xrightarrow[]{C_2H_5O^-}{(CH_3)}_2CHCH_2OC_2H_5 + Br^-}\) |
The mechanisms of reactions (i) and (ii) are, respectively:
The correct order of increasing C-X bond reactivity toward nucleophiles among the following is:
I | II | ||
III | \(\left(\mathrm{CH}_3\right)_3 \mathrm{C}-\mathrm{X}\) | IV | \(\left(\mathrm{CH}_3\right)_2 \mathrm{CH}-\mathrm{X}\) |
1. | I < II < IV < III | 2. | II < III < I < IV |
3. | IV < III < I < II | 4. | III < II < I < IV |
Which of the following reactions cannot form new carbon-carbon bonds?
1. Reimer-Tiemann reaction
2. Cannizaro reaction
3. Wurtz reaction
4. Friedel-Crafts acylation
\(C_6H_5CH_2Br \xrightarrow[2.~H_3O^+] {1.Mg,Ether}~\mathrm X, \)
The product 'X' in the above reaction is:
1. \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{OH} \)
2. \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_3 \)
3. \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{C}_6 \mathrm{H}_5 \)
4. \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{OCH}_2 \mathrm{C}_6 \mathrm{H}_5\)
For the following:
(i) I-
(ii) Cl-
(iii) Br-
The increasing order of nucleophilicity would be:
1. I-<Br-<Cl-
2. Cl-<Br-<I-
3. I- <Cl-<Br-
4. Br-<Cl-<I-
Which of the following undergoes nucleophilic substitution exclusively by SN1 mechanism?
1. Ethyl chloride
2. Isopropyl chloride
3. Benzyl chloride
4. Chlorobenzene
The –OH group of an alcohol or the carboxylic acid can be replaced by – Cl using:
1. | Hypochlorous acid | 2. | Chlorine |
3. | Hydrochloric acid | 4. | Phosphorous pentachloride |