The enthalpy and entropy change for the reaction :

Br₂ (l) + Cl₂ (g)$\to$ 2BrCl (g)

are 30 kJ mol^-1 and 105 J K^-1 mol^-1 respectively.

The temperature at which the reaction will be in equilibrium is :

Entropy decreases during:

1. Crystallization of sucrose from solution

2. Rusting of iron

3. Melting of ice

4. Vaporization of camphor

Match the following process with entropy change

Codes

For the reaction, $2C{}^{}\to C{}^{}$, the value of ∆H and ∆S  are respectively -

1. $∆\mathrm{H}=0$ $,$ $∆\mathrm{S}=-\mathrm{ve}$

2. $∆\mathrm{H}=0$ $,$ $∆\mathrm{S}=0$

3. $∆\mathrm{H}=$ $-\mathrm{ve}$ $,$ $∆\mathrm{S}$ $=$ $-\mathrm{ve}$

4. $∆\mathrm{H}=$ $+\mathrm{ve}$ $,$ $∆\mathrm{S}=$ $+\mathrm{ve}$

Match the following parameters with a description for spontaneity.

Codes

The entropy change in the isothermal reversible expansion of 2 moles of an ideal gas from 10 to 100 L at 300 K is

1. $42.3 \mathrm{J} {\mathrm{K}}^{-1}$

2. $35.8 \mathrm{J} {\mathrm{K}}^{-1}$

3. $38.3 \mathrm{J} {\mathrm{K}}^{-1}$

4. $32.3 \mathrm{J} {\mathrm{K}}^{-1}$

Change in entropy is negative for:

1. Bromine (l)$\to$Bromine(g)

2. C(s) + H₂O(g) $\to$CO(g) + H₂(g)

3. N₂(g,10 atm)$\to$N₂(g,1 atm) 

4. Fe ( 1mol, 400 K) $\to$ Fe( 1mol, 300 K)

1 mole of an ideal gas at 25$°\mathrm{C}$ is subjected to expand reversibly ten times of its initial volume. The change in entropy of expansion is:

1. 19.15 JK^-1mol^-1                         

2. 16.15 JK^-1mol^-1

3. 22.15 JK^-1mol^-1                         

4. None of the above