Given the following reaction:
\(4H(g)\)→  \(2 H_{2}\)\((g)\)
The enthalpy change for the reaction is -869.6 kJ. The dissociation energy of the H-H bond is:
1. -869.6 kJ
2. +434.8kJ
3. +217.4kJ
4. -434.8 kJ

Subtopic:  Enthalpy & Internal energy |
 68%
From NCERT
AIPMT - 2011

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From the following bond energies:
H—H bond energy: 431.37 kJ mol-1 
C=C bond energy: 606.10 kJ mol-1 
C—C bond energy: 336.49 kJ mol-1 
C—H bond energy: 410.50 kJ mol-1 
Enthalpy for the reaction, 

will be:

1. 1523.6 kJ mol-1 2. -243.6 kJ mol-1
3. -120.0 kJ mol-1 4. 553.0 kJ mol-1
Subtopic:  Thermochemistry |
 75%
From NCERT
AIPMT - 2009

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The values of ΔH and ΔS for the given reaction are 170 kJ and 170 JK-1, respectively.
C(graphite) + CO2(g)→2CO(g) 
This reaction will be spontaneous at:

1. 710 K
2. 910 K
3. 1110 K
4. 510 K

Subtopic:  Gibbs Energy Change |
 88%
From NCERT
AIPMT - 2009

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The standard free energies of formation(in kJ/mol) at 298 K are -237.2, -394.4, and -8.2 for H2O(l), CO2(g), and pentane (g), respectively. The value of Ecell for the pentane-oxygen fuel cell is:

1. 1.968 V
2. 2.0968 V
3. 1.0968 V
4. 0.0968 V

Subtopic:  Gibbs Energy Change |
 54%
From NCERT
AIPMT - 2008

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The bond energy of H—H and Cl-Cl is 430 kJ mol-1 and 240 kJ mol-1 respectively
and ΔHf for HCl is -90 kJ mol-1. The bond enthalpy of HCl is:

1. 290 kJ mol-1

2. 380 kJ mol-1

3. 425 kJ mol-1

4. 245 kJ mol-1

Subtopic:  Thermochemistry |
 60%
From NCERT
AIPMT - 2007

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Two moles of an ideal gas is heated at a constant pressure of one atmosphere from 27°C to 127°C. If Cv, m=20+10-2 T JK-1 mol-1,  then q and U for the process are respectively:

1.  6362.8 J, 4700 J

2.  3037.2 J, 4700 J

3.  7062.8 J, 5400 J

4.  3181.4 J, 2350 J

Subtopic:  Cp & Cv |

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Calculate fH° (in kJ/mol) for Cr2O3 from the rG° and the S° values provided at 27°C

4Crs+3O2g  2Cr2O3s; 
rG°=-2093.4 kJ/mol

S°J/K mol : S°Cr, s=24; 
S°O2, g=205;   S°Cr2O3, s=81

1.  -2258.1 kJ/mol

2.  -1129.05 kJ/mol

3.  -964.35 kJ/mol

4.  None of the above

Subtopic:  Gibbs Energy Change |
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The standard heat of combustion of propane is –2220.1 kJ mol–1. The standard heat of vaporisation of liquid water is 44.0 kJ mol–1. The enthalpy change for the reaction is–

C3H8 (g) + 5O2 (g) 3CO2 (g) + 4H2O(g)

1. –2220.1 kJ 2. –2044.1 kJ
3. –2396.1 kJ 4. –2176.1 kJ
Subtopic:  Thermochemistry |

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Which of the following statements is correct for the spontaneous adsorption of a gas?

1. ∆ S is negative and therefore,  ∆ H should be highly positive
2. ∆ S is negative and therefore,  ∆ H should be highly negative
3. ∆ S is positive and therefore,  ∆ H should be negative
4. -∆ S is positive and therefore,  ∆ H should also be highly positive

Subtopic:  Spontaneity & Entropy |
 56%
From NCERT
AIPMT - 2014

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Given the Gibbs free energy change, \(\Delta \text G^\circ=+63.3~\text{kJ},\) for the following reaction, 
\(\mathrm{Ag_2 CO_3 (g) \rightarrow 2Ag^+ (aq) + CO^{2-}_3 (aq)}\)
\(\mathrm{K_{sp}}\) of \(\mathrm {Ag_2CO_3 (s) }\) in water at 25º C is (R = 8.314 JK–1 mol–1)
1. \(3.2 \times 10^{26}\)
2. \(8.0 \times 10^{-12}\)
3. \(2.9 \times 10^{-3}\)
4. \(7.9 \times 10^{-2}\)
Subtopic:  Gibbs Energy Change |
 60%
From NCERT
AIPMT - 2014

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