| List-I | List-II | ||
| A. | \([{Pt(NH_3)_2Cl_2}]\) | I. | Optical |
| B. | \([Co(en)_3]^{3+}\) | II. | Solvate |
| C. | \([Co(NH_3)_5NO_2]Cl_2\) | III. | Geometrical |
| D. | \([Cr(H_2O)_6]Cl_3\) | IV. | Linkage |
| Statement-I: | [Fe(ox)3]3- is chiral. |
| Statement-II: | trans-[Cr(H2O)2(ox)2]- is chiral. |
| 1. | Statement-I is incorrect but Statement-II is correct. |
| 2. | Both Statement-I and Statement-II are correct. |
| 3. | Both Statement-I and Statement-II are incorrect. |
| 4. | Statement-I is correct but Statement-II is incorrect. |
| 1. | [Ni(en)2(H2O)2]2+ |
| 2. | [Cr(py)3(Cl)3] |
| 3. | [Cr(H2O)6]3+ |
| 4. | [Co(NH3)4(H2O)2]3+ |
| 1. | \([Co(NH_3)_3(NO_2)_3]\) |
| 2. | \([CoCl_2(NH_3)_4]Cl\) |
| 3. | \([CoCl(NH_3)_5]Cl_2\) |
| 4. | \([Co(NH_3)_6]Cl_3\) |
| List-I (Complex) | List-II (Type of isomerism) |
||
| A. | \(\mathrm{\left[{Co}\left({NH}_3\right)_5\left({NO}_2\right)\right] {Cl}_2}\) | I. | Solvate isomerism |
| B. | \(\mathrm{\left[{Co}\left({NH}_3\right)_5\left({SO}_4\right)\right] {Br}}\) | II. | Linkage isomerism |
| C. | \(\mathrm{\left[{Co}\left({NH}_3\right)_6\right]\left[{Cr}({CN})_6\right]}\) | III. | Ionization isomerism |
| D. | \(\mathrm{\left[{Co}\left({H}_2 {O}\right)_6\right] {Cl}_3}\) | IV. | Coordination isomerism |
| List-I (Complexes) | List-II (Type of isomer) | ||
| A. | [Co(NH3)5NO2]Cl2 and [Co(NH3)5ONO]Cl2 |
I. | Ionisation isomerism |
| B. | [Cr(NH3)6] [Co(CN)6] and [Cr(CN)6][Co(NH3)6] |
II. | Coordination isomerism |
| C. | [Co(NH3)5(SO4)]Br and [Co(NH3)5Br]SO4 |
III. | Linkage isomerism |
| D. | [Cr(H2O)6]Cl3 and [Cr(H2O)5Cl]Cl2.H2O |
IV. | Solvate isomerism |
| (A) | (B) | (C) | (D) | |
| 1. | (III) | (I) | (II) | (IV) |
| 2. | (II) | (III) | (IV) | (I) |
| 3. | (III) | (II) | (I) | (IV) |
| 4. | (IV) | (III) | (II) | (I) |
| 1. | Geometrical isomerism | 2. | Coordination isomerism |
| 3. | Ionization isomerism | 4. | Linkage isomerism |
The number of possible isomers for the complex \([Co (en)_ 2 Cl_ 2] 𝐶 𝑙 \) will be:
(en=ethylenediamine)
| 1. | Two (2) | 2. | One (1) |
| 3. | Three (3) | 4. | Four (4) |
An anticancer agent among the following is:
| 1. | \(\text { mer} - \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3 \mathrm{Cl}\right] \) | 2. | \(\text { cis -} \left[\mathrm{PtCl}_2\left(\mathrm{NH}_3\right)_2\right] \) |
| 3. | \(\text {cis -} \mathrm{K}_2\left[\mathrm{Pt} \mathrm{Cl}_2 \mathrm{Br}_2\right] \) | 4. | \(\mathrm{NH}_2 \mathrm{CoCl}_4\) |