With a ground state energy of –13.6 eV for a hydrogen atom, what would be the energy in the second excited state?

1.  –6.8 eV 

2. –3.4 eV 

3. –1.51 eV 

4. –4.53 eV 

Subtopic:  Hydrogen Spectra |
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Consider the ground state of Cr atom (Z=24). The numbers of electrons with the azimuthal quantum numbers, l=1 and 2 are, respectively:

1. 12 and 4

2. 12 and 5

3. 16 and 4

4. 16 and 5

Subtopic:  Quantum Numbers & Schrodinger Wave Equation |
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According to Bohr's theory, what is the angular momentum of an electron located in the fifth orbit? 

1. 25hπ

2. 1.0hπ

3. 10hπ

4. 2.5hπ

Subtopic:  Bohr's Theory |
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Uncertainty in the position of a moving particle is 10-7 m and uncertainty velocity is 2.4 × 10-24 m/sec, then the mass of a particle is [X] × 10-5 kg.The  value of X is:
[Report your answer to the nearest integer]

1. 26
2. 19
3. 28
4. 22
Subtopic:  Heisenberg Uncertainty Principle |
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How many sets of quantum numbers are possible?
 
n l m
(a). 2 2 1
(b). 3 2 -2
(c). 3 2 -1
(d). 2 1 -1

1. 0 
2. 1
3. 2 
4. 3 
Subtopic:  Quantum Numbers & Schrodinger Wave Equation |
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Given below are two statements:
Statement I:  h\(\)v = (E2-E1) absorbs a photon.
Statement II:  hv = (E2-E1) = emitted a photon.
 In the light of the above statements, choose the correct answer from the option given below:

1. Both Statement I and Statement II are true.
2. Both Statement I and Statement II are false.
3. Statement I is true but Statement II is false.
4. Statement I is false but Statement II is true.
Subtopic:  Bohr's Theory | Hydrogen Spectra |
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The set of a quantum number that represents degenerate orbitals is: 
 
a. \( \small{n=3, \ell=2, m=0, s=\frac{-1}{2} \,\& \ \,n=3, \ell=2, m=-1, s=\frac{+1}{2}}\)
b. \(\small{n=2, \ell=1, m=1 , \ s=\frac{-1}{2}\, \&\, \ n=3, \ell=1, m=1 \mathrm{~s}=\frac{+1}{2}}\)
c. \(\small{n=4, \ell=2, m=-1, s=\frac{1}{2}\, \&\, \ n=3, \ell=2, m=-1, s=\frac{1}{2}}\)

1. a 
2. b 
3. c 
4. a, b 
Subtopic:  Quantum Numbers & Schrodinger Wave Equation |
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The total energy of 1 mol of photons in J/mol having \(\lambda = 600 \ nm \) is:

Given: \(h = 6.62 \times 10^{-34} \mathrm{~J} \ \mathrm{sec}, \mathrm{c}=3 \times 10^{8} \mathrm{~m \ s}^{-1}\)

1. \(2 \times 10^5 J/mol\)
2. \(6.64 \times 10^8 J/mol\)
3. \(1.24 \times 10^4 J/mol\)
4. \(1.24 \times 10^8 J/mol\)
Subtopic:  Electromagnetic Radiation |
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Using the following statements, identify the correct set of statements:
(i). n (principal quantum number) can have values 1, 2, 3, 4, .......
(ii). The number of orbitals for a given value of l is (2l+1).
(iii). The value of spin quantum numbers is always \(\pm\frac12\).
(iv). For l=5, the total number of orbitals is 9.

1.  (i), (ii), (iii)
2.  (i), (ii), (iv)
3.  (i), (ii), (iii), (iv)
4.  (i), (iii), (iv)
Subtopic:  Quantum Numbers & Schrodinger Wave Equation |
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The correct relation between the radius of 3rd and 4th Bohr orbit for H-atom is:

1.  \(\frac{r_3}{r_4}=\frac{16}{9} \)
2.  \(\frac{r_3}{r_4}=\frac{9}{16} \)
3.  \(\frac{r_3}{r_4}=\frac{9}{4} \)
4.  \(\frac{r_3}{r_4}=\frac{3}{16} \)
Subtopic:  Hydrogen Spectra |
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