The incorrect statement(s) among the below is/are:

(a) The unit of conductivity is S cm–2
(b) Specific Conductivity of weak and strong electrolytes always decreases with a decrease in concentration
(c) The unit of molar conductivity is S cm2 mol–1
(d) Molar conductivity increases with an increase in concentration


1. Only (a)

2. (a) and (d)

3. (b) and (d)

4. (a) and (c)

Subtopic:  Conductance & Conductivity |
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Level 2: 60%+
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The conductivity of 0.20 M solution of KCl at 298 K is 0.0248 S cm–1. The molar conductivity will be -

1. 124 S cm2 mol-1 2. 134 S cm2 mol-1
3. 128 S cm2 mol-1 4. 136 S cm2 mol-1
Subtopic:  Conductance & Conductivity |
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Level 1: 80%+
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The electricity required in coulombs for the oxidation of 1 mole of FeO to \(Fe_{2} O_{3 }\) is:

1. 964.87 C 2. 96487 C
3. 96.487 C 4. 9.6487 C
Subtopic:  Faraday’s Law of Electrolysis |
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\(Fe^{2+}(aq) \ + \ Ag^{+}(aq) \ \rightarrow \ Fe^{3+}(aq) \ + \ Ag(s)\)

\(E_{Fe^{3+}/Fe^{2+}}^{o} \ = \ 0.77 \ V; \ E_{Ag^{+}/Ag}^{o} \ = \ 0.80 \ V\)

The value of \(\Delta G_{r}^{o} \)  in 
the above reaction will be:

1. +2.89 kJ

2. -2.89 kJ

3. -2.89 J

4. -186.83 J

Subtopic:  Relation between Emf, G, Kc & pH |
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Level 1: 80%+
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The value of Ecell in the reaction below will be:

\(\small{Pt(s)|Br^{-}(0.010 \ M)|Br_{2}(l) \ ||H^{+}(0.030 \ M)|H_{2}(g)(1 \ bar)|Pt(s)}\)

\(E_{Br^{-}/Br_{2}}^{o} \ = \ -1.09 \ V\)

1. +1.298 V

2. –1.398 V

3. –1.298 V

4. –1.198 V
Subtopic:  Nernst Equation |
Level 3: 35%-60%
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The value of  ∆G°  in the reaction below would be:
\(\small{\mathrm{Zn}(\mathrm{s})+\mathrm{Ag}_2 \mathrm{O}(\mathrm{s})+\mathrm{H}_2 \mathrm{O}(\mathrm{l}) \rightarrow \mathrm{Zn}^{+2}(\mathrm{aq})+2 \mathrm{Ag}(\mathrm{s})+2 \mathrm{OH}^{-}(\mathrm{aq})}\)


Given: \(E_{cell}^{\circ} = 1.04V\)

1. 2.13 kJ

2. 21.3 kJ

3. 201 kJ

4. 31.12 kJ

Subtopic:  Relation between Emf, G, Kc & pH |
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The coulombs of charge required for the oxidation of 1 mole of H2O2 to O2 is: 

1. 9.65×104 C

2. 93000 C

3. 1.93×105 C

4. 19.3×102 C

Subtopic:  Faraday’s Law of Electrolysis |
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Consider the following graph.

 

The strong electrolyte in the above graph is represented by:

1. X

2. Y

3. Both X and Y

4. Data given is not sufficient to predict.

Subtopic:  Conductance & Conductivity |
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Consider the following graph of molar conductivity of KCl solution at different concentrations. 

 

The value of limiting molar conductivity for KCl is 150.0 S cmmol-1. The value of the slope at point A will be : 

1. 120 2. 100
3. 110 4. None of the above

Subtopic:   Kohlrausch Law & Cell Constant |
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Level 3: 35%-60%
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 2Cr(s) + 3Cd2+(aq)  2Cr3+(aq) + 3Cd

ECr3+/Cr= -0.74 VECd2+/Cd=-0.40 V

The value of Gro in the above reaction will be-

1. -196.83 kJ

2. 196.83 kJ

3. 186.83 kJ

4. -186.83 kJ

Subtopic:  Relation between Emf, G, Kc & pH |
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Level 2: 60%+
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