| List-I (Anions) | List-II (Gas evolved on reaction with dil H2SO4) |
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| A. | \(\mathrm{CO}_3^{2-}\) | I. | Colourless gas that turns lead acetate paper black. |
| B. | \(\mathrm{S}^{2-}\) | II. | Colourless gas that turns acidified potassium dichromate solution green. |
| C. | \(\mathrm{SO}_3^{2-}\) | III. | Brown fumes that turn acidified \(\mathrm{KI}\) solution containing starch blue. |
| D. | \(\mathrm{NO}_2^{-}\) | IV. | Colourless gas evolved with brisk effervescence, which turns lime water milky. |
| 1. | A dark brown ring is formed at the junction of two solutions. |
| 2. | Ring is formed due to nitroso ferrous sulphate complex. |
| 3. | The brown complex is \(\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_5(\mathrm{NO})\right]{\mathrm{SO}_4}\) |
| 4. | Heating the nitrate salt with conc. \(\text{H}_2\text{SO}_4,\) light brown fumes are evolved. |