The standard free energies of formation(in kJ/mol) at 298 K are -237.2, -394.4, and -8.2 for H2O(l), CO2(g), and pentane (g), respectively. The value of Ecell for the pentane-oxygen fuel cell is:

1. 1.968 V
2. 2.0968 V
3. 1.0968 V
4. 0.0968 V

Subtopic:  Gibbs Energy Change |
 54%
From NCERT
AIPMT - 2008
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The values of ΔH and ΔS for the given reaction are 170 kJ and 170 JK-1, respectively.
C(graphite) + CO2(g)→2CO(g) 
This reaction will be spontaneous at:

1. 710 K
2. 910 K
3. 1110 K
4. 510 K

Subtopic:  Gibbs Energy Change |
 88%
From NCERT
AIPMT - 2009
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From the following bond energies:
H—H bond energy: 431.37 kJ mol-1 
C=C bond energy: 606.10 kJ mol-1 
C—C bond energy: 336.49 kJ mol-1 
C—H bond energy: 410.50 kJ mol-1 
Enthalpy for the reaction, 

will be:

1. 1523.6 kJ mol-1 2. -243.6 kJ mol-1
3. -120.0 kJ mol-1 4. 553.0 kJ mol-1
Subtopic:  Thermochemistry |
 75%
From NCERT
AIPMT - 2009
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The correct statement for a reversible process in a state of equilibrium is:
1. G = – 2.30RT log K
2. G = 2.30RT log K
3. Go = – 2.30RT log K
4. Go = 2.30RT log K

Subtopic:  Gibbs Energy Change |
 78%
From NCERT
NEET - 2015
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Which of the following is correct for isothermal expansion of an ideal gas:

1. Wrev = Wirr

2. Wrev + Wirr = 0

3. Wrev > Wirr

4. qrev = qirr

Subtopic:  First Law of Thermodynamics |
 67%
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Which, among the following, is not a state function?

1. Internal energy

2. Free energy

3. Work

4. Enthalpy

Subtopic:  Thermodynamics' Properties and process |
 88%
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Which among the following state functions is an extensive property of the system?

1. Temperature 2. Volume
3. Refractive index 4. Viscosity
Subtopic:  Classification of System, Extensive & Intensive Properties |
 78%
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The bond energies of CC, C-H, H-H, and C=C are 198, 98, 103 and145 kcal respectively.

The enthalpy change of the reaction HCCH+H2C2H4 would be-

1. 48 kcal

2. 96 kcal

3. -40 kcal

4. -152 kcal

Subtopic:  Enthalpy & Internal energy |
 77%
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As an isolated box, equally partitioned, contains two ideal gasses A and B as shown:

 

When the partition is removed, the gases mix. The changes in enthalpy (H) and entropy (S) in the process, respectively, are

1. Zero, positive

2. Zero, negative

3. Positive, zero

4. Negative, zero

Subtopic:  Enthalpy & Internal energy |
 77%
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The entropy change in the isothermal reversible expansion of 2 moles of an ideal gas from 10 to 100 L at 300 K is

1. 42.3 J K-1

2. 35.8 J K-1

3. 38.3 J K-1

4. 32.3 J K-1

Subtopic:  Spontaneity & Entropy |
 70%
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