A hypothetical electrochemical cell is shown below.
A|A⁺(x M) || B⁺(y M)|B
The Emf measured is +0.20 V. The cell reaction is:

1. A⁺ + B → A + B⁺

2.  A⁺ + e^- → A ; B⁺ + e^- → B

3. The cell reaction cannot be predicted.

4. A + B⁺ → A⁺ + B

The concentration of $ZnC{l}_2$ solution will change when it is placed in a container which is made of: