For a given reaction, 
Cu(s) + 2Ag⁺ (aq) → Cu²⁺(aq)+2Ag(s); 
E⁰=0.46 V at 298 K . The equilibrium constant will be :

1.	$2.4\times {10}^{10}$	2.	$2.0\times {10}^{10}$
3.	$4.0\times {10}^{10}$	4.	$4.0\times {10}^{15}$

If ${\mathrm{E}}_{{\mathrm{Fe}}^{2+}/\mathrm{Fe}}^{\mathrm{o}}$ = -0.441 V and  ${\mathrm{E}}_{{\mathrm{Fe}}^{3+}/{\mathrm{Fe}}^{2+}}^{\mathrm{o}}$ = 0.771 V, the standard emf of the reaction: 

Fe + 2Fe³⁺→ 3Fe²⁺ will be:

A hypothetical electrochemical cell is shown below.
A|A⁺(x M) || B⁺(y M)|B
The Emf measured is +0.20 V. The cell reaction is:

1. A⁺ + B → A + B⁺

2.  A⁺ + e^- → A ; B⁺ + e^- → B

3. The cell reaction cannot be predicted.

4. A + B⁺ → A⁺ + B

Given the following cell reaction:
 \(\mathrm{2Fe^{3+}(aq) \ + \ 2I^{-}(aq)\rightarrow 2Fe^{2+}(aq) \ + \ I_{2}(aq)}\)

[Given: \(F  = 96500\) \(C\) \(mol^{- 1}\)]

1. \(23 . 16\) \(kJ\) \(mol^{- 1}\)

2. \(- 46 . 32\) \(kJ\) \(mol^{- 1}\)

3. \(- 23 . 16\) \(kJ\) \(mol^{- 1}\)

4. \(46 . 32\) \(kJ\) \(mol^{- 1}\)

For a cell involving one electron \(E_{cell}^{\ominus} = 0 . 59  V\) at 298 K. The equilibrium constant for the cell reaction is :
\(\mathrm{[Given~ that~ \frac {2.303 ~RT}{F} = 0.059 ~V~ at~ T = 298 K]}\)

A steady current of 1.5 A flows through a copper voltmeter for 10 min. If the electrochemical equivalent of copper is 30 × 10^-5 g C^-1, the mass of copper deposited on the electrode will be:

1. 0.40 g

2. 0.50 g

3. 0.67 g

4. 0.27 g

Kohlrausch's law states that at:

Given:
(i) ${\mathrm{Cu}}^{2+}+2{\mathrm{e}}^{-}\to \mathrm{Cu}$    E^o = 0.337 V 
(ii) ${\mathrm{Cu}}^{2+}+{\mathrm{e}}^{-}\to {\mathrm{Cu}}^{+}$  E^o = 0.153 V 
Electrode potential, E^o for the reaction, 
${\mathrm{Cu}}^{+}+{\mathrm{e}}^{-}\to \mathrm{Cu}$, will be: 

1. 0.52 V

2. 0.90 V

3. 0.30 V

4. 0.38 V