The electronic arrangement of an octahedral complex with a d4 configuration, if 0 < pairing energy is:

1. t2g4eg0                       

2. eg4t2g0               

3. t2g3eg1           

4. eg2t2g2

Subtopic:  VBT, CFT & their Limitations |
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Which among the following is incorrect?

Complex compounds Type of hybridization
1. [V(NH3)6]3+ d2sp3
2. [CrCl3(NMe3)3] d2sp3
3. [Cu(CN)(NO2)(NH3)(py)] dsp2
4. K3[Co(ox)3] sp3d2
Subtopic:  VBT, CFT & their Limitations |
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The incorrect option among the following is:

1.  [Co(NO2)(H2O)(en)2]Cl2, [CoCl(NO2)(en)2]Cl·H2O Hydrate isomerism
2.  [Cu(NH3)4[PtCl4], [CuCl(NH3)3][PtCl3(NH3)] Co-ordination isomerism
3.  [Ni(CN)(H2O)(NH3)4]Cl, [NiCl(H2O)(NH3)4]CN Ionization isomerism
4.  [Cr(NO2)(NH3)5][ZnCl4], [Cr(NO3)(NH3)5][ZnCl4] Linkage isomerism
Subtopic:  Ligands |
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The correct IUPAC name among the following is:

1. Tris(acetylacetonato)iron(III) chloride
2. Hexachloroplatinum(IV) tetraamminedicyanoplatinate(IV)
3. Amminebromochloromethylamineplatinum(II) 
4. cis-dichloro(ethylenediamine) platinum(II)
Subtopic:  Introduction, Classification and Nomenclature |
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Correct IUPAC name for H2[PtCl6] is:

1. Hydrogen hexachloroplatinate(IV)

2. Dihydrogen hexachloroplatinate(IV)

3. Hydrogen hexachloroplatinic(IV) acid

4. Hexachloroplatinic(IV) acid

Subtopic:  Introduction, Classification and Nomenclature |
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[Fe(H2O)6]2+ and [Fe(CN)6]4-  differ in:

1. Geometry and magnetic moment.

2. Geometry and hybridization.

3. Magnetic moment and colour.                       

4. Hybridization and number of d-electrons.

Subtopic:  VBT, CFT & their Limitations |
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Aqueous solution of Ni2+ contains [Ni(H2O)6]2+ and its magnetic moment is 2.83 BM. When ammonia is added in it, the magnetic moment of solution:

1. Will remain the same.

2. Will increase from 2.83 BM.

3. Will decrease from 2.83 BM.

4. Cannot be predicted theoretically.

Subtopic:  VBT, CFT & their Limitations |
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[Co(NH3)4(NO2)2]Cl can show:

1. Linkage isomerism, ionization isomerism and optical isomerism.
2. Linkage isomerism, ionization isomerism and geometrical isomerism.
3. Ionisation isomerism, geometrical isomerism and optical isomerism.
4. Ionisation isomerism, geometrical isomerism and optical isomerism.

Subtopic:  Isomerism in Coordination Compounds |
 78%
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NEET - 2006
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oct(CFSE in the octahedral field) will be maximum in:
(Atomic number Co = 27)

1. [Co(H2O)6]3+

2. [Co(NH3)6]3+

3. [Co(CN)6]3-

4. [Co(C2O4)3]3-

Subtopic:  VBT, CFT & their Limitations |
 66%
From NCERT
NEET - 2008
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The complex that does not exhibit optical isomerism is:

(en-ethylenediamine)

1. [Co(en)2Cl2]+

2. [Co(NH3)3Cl3]

3. [Co(en)Cl2(NH3)2]+

4. [Co(en)3]3+

Subtopic:  Isomerism in Coordination Compounds |
 65%
From NCERT
NEET - 2009
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