| Assertion (A): | When methanol is added to water, the boiling point of water increases |
| Reason (R): | When a volatile solute is added to a volatile solvent, an elevation in boiling point is observed. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | Both (A) and (R) are False. |
| Assertion (A): | 0.1 M solution of glucose has the same decrement in the freezing point as 0.1 M solution of urea. |
| Reason (R): | Kf for both has the same value. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | Both (A) and (R) are False. |
| Assertion (A): | When an ideal binary solution is in equilibrium with its vapour, the molar ratio of the two components in the solution and in the vapour phase may or may not be the same. |
| Reason (R): | The vapour pressure of a solution depends upon the vapour pressures of volatile components. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | Both (A) and (R) are False. |
| Assertion (A): | Azeotropes have a different composition in liquid and vapour state. |
| Reason (R): | The composition in both the liquid and the vapour phase depends upon the volatility of the substance. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True and (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | Both (A) and (R) are False. |
| List-I (Types of Solutions) |
List-II (Common Examples) |
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| A. | Gas in Gas | I. | Solution of hydrogen in palladium |
| B. | Solid in Gas | II. | Mixture of oxygen and nitrogen gas |
| C. | Gas in Liquid | III. | Camphor in nitrogen gas |
| D. | Gas in Solid | IV. | Oxygen dissolved in water |
| Options: | A | B | C | D |
| 1. | II | III | IV | I |
| 2. | II | I | IV | III |
| 3. | II | IV | III | I |
| 4. | II | IV | I | III |
| Statement I: | The mass of a gas dissolved in a given mass of a solvent at any temperature is proportional to the pressure of the gas above the solvent. |
| Statement II: | The rate of dissolution of sugar is equal to the rate of crystallization of sugar at equilibrium. |
| 1. | Both statement I and statement II are true. |
| 2. | Both statement I and statement II are false. |
| 3. | Statement I is true but statement II is false. |
| 4. | Statement I is false but statement II is false. |
| List-I (Concentration expression) |
List-II (Uses) |
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| A. | Mass percentage | I. | Medicine |
| B. | Volume percentage | II. | Concentration of pollutants |
| C. | Mass by volume percentage |
III. | Industrial chemicals |
| D. | Parts per million | IV. | Liquid solutions |
| Options: | A | B | C | D |
| 1. | III | IV | II | I |
| 2. | III | II | IV | I |
| 3. | III | IV | I | II |
| 4. | III | I | II | IV |
| Assertion (A): | The people living at high altitudes or climbers have a high concentration of oxygen in their blood and tissues. |
| Reason (R): | At high altitudes, the partial pressure of oxygen is less than that at the ground level. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
| Column-I | Column-II | ||
| A. | Rate constant (k) of a second-order reaction | I. | m3mol-1 |
| B. | Cryoscopic constant (Kf) | II. | mol-1L s-1 |
| C. | Van der Waals constant (b) | III. | No units |
| D. | Compressibility factor (Z) | IV. | kg K mol-1 |
| Options: | (A) | (B) | (C) | (D) |
| 1. | II | IV | I | III |
| 2. | III | IV | II | I |
| 3. | II | III | IV | I |
| 4. | IV | I | II | III |