The positive deviations from Raoult’s law mean the vapour pressure is:
1. Higher than expected.
2. Lower than expected.
3. As expected.
4. None of the above
The type of inter-molecular interactions present in:
| (a) | n-Hexane and n-octane | (i) | Van der Waal’s forces of attraction |
| (b) | NaClO4 and water | (ii) | Ion-dipole interaction |
| (iii) | Dipole-dipole interaction |
| (a) | (b) | |
| 1. | (i) | (ii) |
| 2. | (ii) | (ii) |
| 3. | (i) | (iii) |
| 4. | (iii) | (iii) |
The amount of benzoic acid (C6H5COOH) required for preparing 250 mL of 0.15 M solution in methanol is:
| 1. | 4.57 g | 2. | 3.57 g |
| 3. | 1.57 g | 4. | 12.57 g |
Henry’s law constant for the solution of methane in benzene at 298 K is 4.27 × 105 mm Hg. The mole fraction of methane in benzene at 298 K under 760 mm Hg will be:
1. 1.85 × 10–5
2. 192 × 10–4
3. 178 × 10–5
4. 18.7 × 10–5
The solubility of \(H_2S\) in water at STP is 0.195 m. The value of Henry's constant is:
| 1. | 274 atm | 2. | 285 atm |
| 3. | 295 atm | 4. | 278 atm |
The solubility of gases in liquids generally decreases as temperature increases.
The primary reason for this behavior is:
| 1. | Dissolution of a gas in a liquid is an endothermic process. |
| 2. | Dissolution of a gas in a liquid is an exothermic process. |
| 3. | Gases are highly compressible. |
| 4. |
All of the above statements are correct. |
Which law is applied when deep-sea divers use a breathing mixture of oxygen and less soluble helium to minimise the painful effects caused by the increased dissolution of gases in blood at high pressure?
| 1. | Raoult's law | 2. | Henry's law |
| 3. | Ideal gas Equation | 4. | All of the above |
| Type of solution | Example | ||
| a. | Solid in gas | i. | Aerated water |
| b. | Gas in liquid | ii. | Smoke |
| c. | Liquid in solid | iii. | Solution of hydrogen in palladium |
| d. | Gas in solid | iv. | Amalgams |
| a | b | c | d | |
| 1. | i | iii | iv | ii |
| 2. | ii | i | iv | iii |
| 3. | iii | i | iv | ii |
| 4. | iv | i | ii | iii |
A solution of glucose (M.W. = 180 g mol–1) in water is 10 % w/w. The mole fraction of each component in the solution is:
| 1. | Mole fraction of glucose - 0.44; mole fraction of water - 0.56 |
| 2. | Mole fraction of glucose - 0.056; mole fraction of water - 0.944 |
| 3. | Mole fraction of glucose - 0.011; mole fraction of water - 0.99 |
| 4. | Mole fraction of glucose - 0.36; mole fraction of water - 0.64 |
The type of molecular interactions in a solution of alcohol and water is:
| 1. | Electrostatic interaction | 2. | London dispersion forces |
| 3. | Hydrogen bonding | 4. | Ion-dipole interaction |