The unit cell of copper corresponds to a face-centred cube of edge length 3.596 Å with one copper atom at each lattice point. The calculated density of copper in kg/m3 is-
[Molar mass of Cu : 63.54 g ; Avogadro Number = 6.022× 1023]
1. 9076
2. 9100
3. 8994
4. 9087
The coordination number of an atom in a body-centered cubic structure is-.
[Assume that the lattice is made up of atoms.]
1. 4
2. 6
3. 8
4. 12
The number of octahedral voids per lattice site in a lattice is-
1. 2
2. 1
3. 4
4. 0
An element with molar mass 2.7 × 10–2 kg mol–1 forms cubic unit cell with edge length 405 pm. If its density is 2.7 × 103 kg m–3 , the radius of the element in × 10–12 m is approximately-
1. 148
2. 143
3. 140
4. 152
A diatomic molecule X2 has a body-centred cubic (bcc) structure with a cell edge of 300 pm. The density of the molecule is 6.17 g cm–3 . The number of molecules present in 200 g of X2 is-
(Avogadro constant (NA) = 6 × 1023 mol–1)
1. 8 NA
2. 40 NA
3. 4 NA
4. 2 NA
A crystal is made up of metal ions '' , '', and oxide ions. Oxide ions form a CCP lattice structure. The cation '' occupies 50% of octahedral voids and the cation '' occupies 12.5% of tetrahedral voids of oxide lattice. The oxidation numbers of '' and'' are, respectively :
1. +2, +4
2. +3, +1
3. +1, +3
4. +4, +2
Element ‘B’ forms ccp structure and ‘A’ occupies half of the octahedral voids, while oxygen atoms occupy all the tetrahedral voids. The structure of bimetallic oxide is -
1.
2.
3.
4.