On heating, some solid substances change from solid to vapour state without passing through liquid state. The technique used for the purification of such solid substances based on the above principle is known as :
1. Sublimation
2. Distillation
3. Chromatography
4. Crystallization
 
Subtopic:  Qualitative Analysis of Organic Compounds |
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Match List I with List II.
List I 
(Molecule) 
List II
(Number and types of bond/s between two carbon atoms)
A.  ethane I.  \(\mathrm{one ~\sigma-bond~ and~ two~ \pi-bonds}\)
B.  ethene II.  \(\text { two } \pi \text {-bonds }\)
C.  carbon
molecule, \(\mathrm{C} _2\)
III.  \(\text { one } \sigma \text {-bond }\)
D.  ethyne IV.  \(\mathrm{one ~\sigma-bond ~and ~one~ \pi-bond}\)

Choose the correct answer from the options given below:

1. A-IV, B-III, C-II, D-I
2. A-III, B-IV, C-II, D-I
3. A-III, B-IV, C-I, D-II
4. A-I, B-IV, C-II, D-III
Subtopic:  Hybridisation & Structure of Carbon Compounds |
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A compound with a molecular formula of C6H14 has two tertiary carbons. Its IUPAC name is:

1. 2-methyl pentane
2. 2, 3-dimethylbutane
3. 2, 2-dimethylbutane
4. n-hexane
Subtopic:  Nomenclature |
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The most stable carbocation among the following is :
 
1.
2.
3.
4.
Subtopic:  Reaction Intermediates ; Preparation & Properties |
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Phenanthrene is an aromatic compound and follows Huckel's \((4 n+2) \pi\) electron rule. The value of \(n\) is:
  


1. 0
2. 1
3. 2
4. 3
Subtopic:  Aromaticity & Polarity |
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The method used for quantitative estimation of halogens is:

1. Dumas method
2. Carius method
3. Kjeldahl's method
4. Combustion method
Subtopic:  Qualitative Analysis of Organic Compounds |
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The technique used to purify liquids having high boiling points and getting decomposed at or below their boiling points is:

1. fractional distillation 
2. steam distillation
3. simple distillation
4. distillation under reduced pressure
Subtopic:  Qualitative Analysis of Organic Compounds |
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The compound that gives blood red colour in Lassaigne's test is:
1.
2.
3.
4.

 
Subtopic:  Qualitative Analysis of Organic Compounds |
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In Lassaigne's extract of an organic compound, both nitrogen and sulphur are present, which gives blood red colour with \(\text{Fe}^{3+}\) due to the formation of:

1. \([\mathrm{Fe}(\mathrm{SCN})]^{2+} \)
2. \(\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3 \cdot \mathrm{xH}_2 \mathrm{O} \)
3. \(\mathrm{NaSCN} \)
4. \(\left[\mathrm{Fe}(\mathrm{CN})_5 \mathrm{NOS}\right]^{4-} \)
Subtopic:  Qualitative Analysis of Organic Compounds |
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The number of \(\sigma\)  bonds, \(\pi\) bonds and lone pair of electrons in pyridine respectively are: 
1. 12, 2, 1
2. 11, 2, 0 
3. 12, 3, 0 
4. 11, 3, 1
Subtopic:  Hybridisation & Structure of Carbon Compounds |
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