| 1. | −1.635 kJ mol−1, spontaneous |
| 2. | +0.63568 kJ mol−1, non-spontaneous |
| 3. | −0.63568 kJ mol−1, spontaneous |
| 4. | +1.635 kJ mol−1, non-spontaneous |

| 1. | w₁ + w₂ + w₃ + w₄ = 0 |
| 2. | w₁ + w₃ = -2T₁ ln \(\frac{V₂}{V₁}\) - 2T₂ ln \(\frac{V₄}{V₃}\) |
| 3. | w₂ + w₄ = ΔU₂ - ΔU₄ |
| 4. | w₁ + w₂ = 2T₁ ln \(\frac{V₂}{V₁}\) |
| 1. | \(\Delta \mathrm{S}_{\text {system }}=4.606 \mathrm~{R} ; \Delta \mathrm{S}_{\text {surroundings }}=0\) |
| 2. | \(\Delta \mathrm{~S}_{\text {system }}=0 ;~ \Delta \mathrm{S}_{\text {surroundings }}=0 \) |
| 3. | \(\Delta \mathrm{~S}_{\text {system }}=4.606~ \mathrm{R} ; \Delta \mathrm{S}_{\text {surroundings }}= -4.606 \mathrm{R}\) |
| 4. | \(\Delta \mathrm{~S}_{\text {system }}=0 ; \quad \Delta ~~\mathrm{S}_{\text {surroundings }}= 4.606 \mathrm{R}\) |
| 1. | \(+133.0 \) | 2. | \(+220.5\) |
| 3. | \(-128.5 \) | 4. | \(-133.0\) |
Find the amount of heat released when 35.0 g of CO₂ is formed from the combustion of carbon in dioxygen gas. Given that the enthalpy of combustion of carbon to carbon dioxide is −390.0 kJ mol⁻¹.
| 1. | \(310~\text{kJ}\) | 2. | \(490~\text{kJ}\) |
| 3. | \(245~\text{kJ}\) | 4. | \(700~\text{kJ}\) |
| 1. | Both the heat and work done will be greater than zero. |
| 2. | Heat absorbed will be less than zero and work done will be positive. |
| 3. | Work done will be zero and heat absorbed or evolved will also be zero. |
| 4. | Work done will be greater than zero and heat absorbed will remain zero. |
| 1. | B and D | 2. | C and D |
| 3. | A and B | 4. | A and C |
| 1. | 19.98 K J | 2. | 200 J |
| 3. | 1999 J | 4. | 1.9988 kJ |
| 1. | –413.14 calories | 2. | 413.14 calories |
| 3. | 100 calories | 4. | 0 calorie |