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Statement I: | In the Hofmann rearrangement reaction, the alkyl group shifts from a carbonyl carbon atom to the nitrogen atom. |
Statement II: | The tertiary amine formed in Hofman rearrangement reaction contains one carbon less than that present in the original amide. |
1. | Both Statement I & Statement II are true. |
2. | Both Statement I & Statement II are false. |
3. | Statement I is true while Statement II is false. |
4. | Statement I is false while Statement II is true. |
Assertion (A): | In strongly acidic solutions, aniline becomes more reactive towards electrophilic reagents. |
Reason (R): | The amino group being completely protonated in a strongly acidic solution, the lone pair of electrons on the nitrogen is no longer available for resonance |
1. | Both (A) & (R) are True and the reason is the correct explanation of the (A). |
2. | Both (A) & (R) are True but the reason is not the correct explanation of the (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Amine (List–I) | List - II pKb (aqueous medium) | ||
A. | Aniline | (i) | 9.0 |
B. | Ethanamine | (ii) | 3.29 |
C. | N-Ethylethanamine | (iii) | 3.25 |
D. | N,N-diethylethanamine | (iv) | 3.0 |
A | B | C | D | |
1. | (i) | (ii) | (iv) | (iii) |
2. | (i) | (iv) | (iii) | (ii) |
3. | (i) | (ii) | (iii) | (iv) |
4. | (ii) | (iii) | (iv) | (i) |
The most reactive amine towards dilute hydrochloric acid is:
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