Arrange the following amines in decreasing order of basicity:
(A)   (B) 
(C)  (D) 
1. (A) > (C) > (D) > (B) 
2. (C) > (A) > (B) > (D) 
3. (B) > (C) > (D) > (A) 
4. (C) > (B) > (A) > (D) 
Subtopic:  Amines - Preparation & Properties |
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Consider the given two statements:
Statement I: In the Hofmann rearrangement reaction, the alkyl group shifts from a carbonyl carbon atom to the nitrogen atom. 
Statement II: The tertiary amine formed in Hofman rearrangement reaction contains one carbon less than that present in the original amide.
 
1. Both Statement I & Statement II are true.
2. Both Statement I & Statement II are false.
3. Statement I is true while Statement II is false.
4. Statement I is false while Statement II is true.
Subtopic:  Amines - Preparation & Properties |
From NCERT
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Assertion (A): In strongly acidic solutions, aniline becomes more reactive towards electrophilic reagents.
Reason (R): The amino group being completely protonated in a strongly acidic solution, the lone pair of electrons on the nitrogen is no longer available for resonance
 
1. Both (A) & (R) are True and the reason is the correct explanation of the (A).
2. Both (A) & (R) are True but the reason is not the correct explanation of the (A).
3. (A) is True but (R) is False.
4. (A) is False but (R) is True.
Subtopic:  Amines - Preparation & Properties |
From NCERT
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Match the organic compounds given in List–I with their corresponding pKb given in List–II:
Amine (List–I) List - II pKb (aqueous medium)
A. Aniline (i) 9.0
B. Ethanamine (ii) 3.29
C. N-Ethylethanamine (iii) 3.25
D. N,N-diethylethanamine (iv) 3.0
 
A B C D
1. (i) (ii) (iv) (iii)
2. (i) (iv) (iii) (ii)
3. (i) (ii) (iii) (iv)
4. (ii) (iii) (iv) (i)
Subtopic:  Amines - Preparation & Properties |
From NCERT
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The most reactive amine towards dilute hydrochloric acid is:

1. 2.
3. 4.
Subtopic:  Amines - Preparation & Properties |
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Which of the following will produce the highest yield in Friedel Crafts reaction? 
1.  2. 
3.  4. 
Subtopic:  Amines - Preparation & Properties |
From NCERT
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'x' and 'y' are respectively :

(1) 
(2)
(3)
(4)
Subtopic:  Amines - Preparation & Properties |
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From which of the reactions or compounds given below, aniline cannot be formed?
1. Hoffmanns Bromamide reaction
2. Schmidt reaction
3. 
4. \(R-C \equiv N\)
Subtopic:  Amines - Preparation & Properties |
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In the following reaction sequence,  
 
the major products X and Z are:
 
1.
2.
3.
4.
Subtopic:  Amines - Preparation & Properties | Mechanism |
From NCERT
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\(R-COOH\xrightarrow[(2)~Br_2/KOH]{(1)~ND_3,~\Delta}A~\text(major).\)
The compound \('A'\) is:
1. \(R-COND_2\)
2. \(R-NH_2\)
3. \(R-ND_2\)
4. \(R-CONH_2\)
Subtopic:  Amines - Preparation & Properties |
From NCERT
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