Benzene diazonium chloride on reaction with aniline in the presence of dilute hydrochloric acid gives:

1.  2.  
3.   4.  
 

Subtopic:  Mechanism |
 92%
Level 1: 80%+
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Match the reactions given in Column-I with the statements given in Column-II.

Column-I Column-II
A. Ammonolysis (i) Amine with a lesser number of carbon atoms
B. Gabriel phthalimide synthesis (ii) Detection test for primary amines.
C. Hofmann bromamide reaction (iii) Reaction of phthalimide with KOH and R—X
D. Carbylamine reaction (iv) Reaction of alkyl halides with NH3

Codes:

A B C D
1. (ii) (iii) (iv) (i)
2. (iii) (i) (iv) (ii)
3. (i) (iv) (iii) (ii)
4. (iv) (iii) (i) (ii)
Subtopic:  Diazonium Salts: Preparation, Properties & Uses | Mechanism |
 90%
Level 1: 80%+
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Based on the statements given, which option is correct?

Assertion (A): Nitration of aniline at a low temperature gives 47% m-nitroaniline.
Reason (R): In acidic medium, NH2 group is converted into -N+H3 group which is m-directing.
 
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. Both (A) and (R) are False.
Subtopic:  Mechanism |
 85%
Level 1: 80%+
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The final product C in the reaction mentioned below is:

 \(\xrightarrow[]{Ac_2O}\ A\ \xrightarrow[CH_3COOH]{Br_2}\ B\ \xrightarrow[H^+]{H_2O}\ C\)   
 

1.  2.
3. 4.
Subtopic:  Mechanism |
 66%
Level 2: 60%+
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