${\mathrm{E}}^{\Theta }$ values of some redox couples are given below. On the basis of these values choose the correct option.

${\mathrm{E}}^{\mathrm{\Theta }} \mathrm{values}: {\mathrm{Br}}_2/{\mathrm{Br}}^{-}=+1.90$
${\mathrm{Ag}}^{+}/\mathrm{Ag}\left(\mathrm{s}\right)=+0.80$
${\mathrm{Cu}}^{2+}/\mathrm{Cu}\left(\mathrm{s}\right)=+0.34;$
${\mathrm{I}}_2\left(\mathrm{s}\right)/{\mathrm{I}}^{-}=+0.54$

Given below are two statements: 

Which of the following electrodes will act as anodes, when connected to Standard Hydrogen Electrode?

The correct choice among the above is:

1. (a, b)

2. (b, c)

3. (c, d)

4. (a, d)