What conditions favor the formation of 2XY₄(g) in the reaction X₂(g) + 4Y₂(g) ⇋ 2XY₄(g), considering that the enthalpy change (ΔH) is negative?

1.  Low pressure and low temperature

2.  High temperature and low pressure

3.  High pressure and low temperature

4.  High temperature and high pressure

Subtopic:  Le Chatelier's principle |
 79%
Level 2: 60%+
AIPMT - 2011
Hints

Find the equilibrium constant K for the reaction:

NO₂(g) ⇌ ½N₂(g) + O₂(g)

Given:

N₂(g) + O₂(g) ⇌ 2NO(g), K₁

2NO(g) + O₂(g) ⇌ 2NO₂(g), K₂

1. 4K₁K₂
2. [1/(K₁K₂)]¹ᐟ²
3. 1/(K₁K₂)
4. 1/(2K₁K₂)
Subtopic:  Kp, Kc & Factors Affecting them |
 89%
Level 1: 80%+
AIPMT - 2011
Hints
Links

Calculate the hydrogen ion concentration, [\(\text{H}^+\)] (in \(\text{mol}/\text{L}\)), of a buffer solution prepared by mixing \(0.10 \text{ M}\) acetic acid (\(\text{CH}_3\text{COOH}\)) and \(0.20 \text{ M}\) sodium acetate (\(\text{CH}_3\text{COONa}\)), given that the acid dissociation constant (\(\text{K}_a\)) for acetic acid is \(1.8 \times 10^{-5}\):

1. \(3 . 5 \times 10^{- 4}\)
2. \(1 . 1 \times 10^{- 5}\)
3. \(1 . 8 \times 10^{- 5}\)
4. \(9 . 0 \times10^{- 6}\)

Subtopic:  Buffer |
 53%
Level 3: 35%-60%
AIPMT - 2010
Hints

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The equilibrium reaction that doesn't have equal values for Kc and Kp is: 

1. \(2NO(g) \rightleftharpoons N_2(g) + O_2(g)\)
2. \(SO_2(g) + NO_2(g) \rightleftharpoons SO_3(g) + NO(g)\)
3. \(H_2(g) + I_2(g) \rightleftharpoons 2HI (g)\)
4. \(2C(s) + O_2(g) \rightleftharpoons 2CO_2(g)\)

Subtopic:  Kp, Kc & Factors Affecting them |
 92%
Level 1: 80%+
AIPMT - 2010
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In a buffer solution containing an equal concentration of B- and HB, the Kb for B- is 10-10. pH of the buffer solution is:

1. 10 2. 7
3. 6 4. 4
Subtopic:  Buffer |
 73%
Level 2: 60%+
AIPMT - 2010
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Links

The tendency of BF3, BCl3 and BBr3 to behave as Lewis acid decreases in the sequence:

1. BCl3>BF3>BBr3

2. BBr3>BCl3>BF3

3. BBr3>BF3>BCl3

4. BF3>BCl3>BBr3

Subtopic:  Acids & Bases - Definitions & Classification |
 67%
Level 2: 60%+
AIPMT - 2010
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The ionization constant of ammonium hydroxide is 1.77 x 10-5 at 298 K. Hydrolysis constant of ammonium Chloride is:

1. 5.65 x 10-10 2. 6.50 x 10-12
3. 5.65 x 10-13 4. 5.65 x 10-12
Subtopic:  Salt Hydrolysis & Titration |
 75%
Level 2: 60%+
AIPMT - 2009
Hints

If the concentration of OH ' ions in the reaction 

Fe(OH)3(s)  ⇋ Fe3+(aq) + 3OH-(aq)is 
decreased by 14 times, then the equilibrium concentration of Fe3+ will increase by:

1. 8 times

2. 16 times

3. 64 times

4. 4 times

Subtopic:  Introduction To Equilibrium |
 80%
Level 1: 80%+
AIPMT - 2008
Hints

The dissociation equilibrium of a gas AB2 can be represented as 
 2AB2(g) ⇋ 2AB(g) + B2(g) 
The degree of dissociation is ‘x’ and is small compared to 1. The expression relating the degree of dissociation (x) with equilibrium constant KP and total pressure p is:
1. (2KP/p)
2. (2Kp /p)1/3
3. (2KP/p)1/2
4. (KP/P)

Subtopic:  Kp, Kc & Factors Affecting them |
 70%
Level 2: 60%+
AIPMT - 2008
Hints

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The value of KP1 and Kp2 for the reactions
 X ⇋ Y +Z ......(i)
and A ⇋2B ......(ii) 
are in the ratio of 9 : 1. If the degree of dissociation of X and A is equal, then the total pressure at equilibrium(i) and (ii) are in the ratio:

1. 3 : 1

2. 1 : 9

3. 36 : 1

4. 1 : 1

Subtopic:  Kp, Kc & Factors Affecting them |
 63%
Level 2: 60%+
AIPMT - 2008
Hints