At 25 ºC molar conductance of 0.1 molar aqueous solution of ammonium hydroxide is 9.54 ohm^–1cm² mol^–1 and at infinite dilution, its molar conductance is 238 ohm^–1 cm² mol^–1. The degree of ionization of ammonium hydroxide at the same concentration and temperature are:
1. 20.800%
2. 4.008%
3. 40.800%
4. 2.080%

If half-cell potentials are-

The cell potential will be:

Limiting molar conductivity of NH₄OH (i.e., ${\mathrm{\Lambda }}_{\mathrm{m}\left({\mathrm{NH}}_4\mathrm{OH}\right)}^0$ is equal to -

1. ${\mathrm{\Lambda }}_{\mathrm{m}\left(\mathrm{NaOH}\right)}^0+{\mathrm{\Lambda }}_{\mathrm{m}\left(\mathrm{NaCl}\right)}^0-{\mathrm{\Lambda }}_{\mathrm{m}\left(\mathrm{NaOH}\right)}^0$

2. ${\mathrm{\Lambda }}_{\mathrm{m}\left(\mathrm{NaOH}\right)}^0+{\mathrm{\Lambda }}_{\mathrm{m}\left(\mathrm{NaCl}\right)}^0-{\mathrm{\Lambda }}_{\mathrm{m}\left({\mathrm{NH}}_4\mathrm{Cl}\right)}^0$

3. ${\mathrm{\Lambda }}_{\mathrm{m}\left({\mathrm{NH}}_4\mathrm{OH}\right)}^0+{\mathrm{\Lambda }}_{\mathrm{m}\left({\mathrm{NH}}_4\mathrm{Cl}\right)}^0-{\mathrm{\Lambda }}_{\mathrm{m}\left(HCl\right)}^0$

4. ${\mathrm{\Lambda }}_{\mathrm{m}\left({\mathrm{NH}}_4\mathrm{Cl}\right)}^0+{\mathrm{\Lambda }}_{\mathrm{m}\left(\mathrm{NaOH}\right)}^0-{\mathrm{\Lambda }}_{\mathrm{m}\left(\mathrm{NaCl}\right)}^0$

Standard electrode potential for Sn⁴⁺/Sn²⁺ couple is +0.15 V and that for Cr³⁺/Cr couple is -0.74. These two couples in their standard state are connected to make a cell. The cell potential will be:

1. +0.89 V

2. +0.18 V

3. +1.83 V

4. +1.199 V

For the reduction of silver ions with copper metal, the standard cell potential was found to be +0.46 V at 25 °C. The value of standard Gibbs energy, ΔG^o will be: 

(F = 96500 C mol^-1)

1. -89.0 kJ

2. -89.0 J

3. -44.5 kJ

4. -98.0 kJ

The molar conductance of $\frac{\mathrm{M}}{32}$ solution of a weak monobasic acid is 8.0 ohm^-1 cm² and at infinite dilution is 400 ohm^-1 cm². The dissociation constant of this acid is: 

Given:
(i) ${\mathrm{Cu}}^{2+}+2{\mathrm{e}}^{-}\to \mathrm{Cu}$    E^o = 0.337 V 
(ii) ${\mathrm{Cu}}^{2+}+{\mathrm{e}}^{-}\to {\mathrm{Cu}}^{+}$  E^o = 0.153 V 
Electrode potential, E^o for the reaction, 
${\mathrm{Cu}}^{+}+{\mathrm{e}}^{-}\to \mathrm{Cu}$, will be: 

1. 0.52 V

2. 0.90 V

3. 0.30 V

4. 0.38 V