Which of the following pairs contain species that are not isostructural?
| 1. | \(\mathrm{SiCl}_4, \mathrm{PCl}_4^{+}\) | 2. | Diamond, silicon carbide |
| 3. | \(\mathrm{NH}_3, \mathrm{PH}_3\) | 4. | \(\mathrm{XeF}_4, \mathrm{XeO}_4\) |
Which of the following compounds has a structure similar to graphite?
1. B
2. B4C
3. B2H6
4. BN
Which of the following is not a monomer for a high molecular mass silicone polymer?
| 1. | Me2SiCl2 | 2. | Me3SiCl |
| 3. | PhSiCl3 | 4. | MeSiCl3 |
The basic structural unit of silicates is:
1. (SiO4)4–
2. (SiO3)2–
3. (SiO4)2–
4. (SiO)
Which of the following is least likely to act as a Lewis base?
| 1. | NH3 | 2. | BF3 |
| 3. | OH- | 4. | H2O |
| 1. | Sheet silicate | 2. | Pyrosilicate |
| 3. | Three dimensional silicate | 4. | Linear chain silicate |
Which one of the following anions is present in the chain structure silicates?
1.
2.
3.
4.
Al2O3 can be converted to anhydrous AlCl3 by heating:
1.
2. with NaCl in solid-state
3. a mixture of and carbon in dry gas
4. with gas
Which of the following statements is incorrect?
1. SnF4 is ionic in nature.
2. PbF4 is covalent in nature.
3. SiCl4 is easily hydrolysed.
4. GeX4 (X = F, Cl, Br, I) is more stable than GeX2
The correct order of atomic radii of the group 13 elements is-
1. B < Al < In < Ga < Tl
2. B < Al < Ga < In < Tl
3. B < Ga < Al < Tl < In
4. B < Ga < Al < In < Tl