Q. No.A nitrogen-containing aromatic compound A reacts with Sn/HCl, followed by HNO2 to give an unstable compound B. On treatment with phenol, B forms a beautiful coloured compound C with the molecular formula C12H10N2O. The structure of compound A is:
1.
2.
3.
4.
The correct statement regarding the basicity of arylamines is:
| 1. | Arylamines are generally more basic than alkylamines because the lone-pair electrons of nitrogen are not delocalized by interaction with the aromatic ring π-electron system. |
| 2. | Arylamines are generally more basic than alkylamines because of the aryl group +I effect. |
| 3. | Arylamines are generally more basic than alkylamines because the nitrogen atom in arylamines is sp-hybridized. |
| 4. | Arylamines are generally less basic than alkylamines because the nitrogen lone-pair electrons are delocalized by interaction with the aromatic ring π-electron system. |
Mark the reaction that does not yield aniline from the given options:
| 1. | Hydrolysis of phenyl isocyanide with an acidic solution |
| 2. | Degradation of benzamide with bromine in alkaline solution |
| 3. | Reduction of nitrobenzene with H2/Pd in ethanol |
| 4. | Treatment of potassium salt of phthalimide with chlorobenzene followed by hydrolysis in an aqueous NaOH solution |
What is the name of the following reaction?
1. Friedel-Crafts reaction
2. Perkins reaction
3. Acetylation reaction
4. Schotten-Baumann reaction
The most stable diazonium salt among the following is:
1. \(CH_{3}N_{2}^{+}X^{-}\)
2. \(C_{6}H_{5}N_{2}^{+}X^{-}\)
3. \(CH_{3}CH_{2}N_{2}^{+}X^{-}\)
4. \(C_{6}H_{5}CH_{2}N_{2}^{+}X^{-}\)
Aniline gives a set of the following reactions that yielded a coloured product 'Y':
The structure of 'Y' is :
| 1. |  |
| 2. |  |
| 3. |  |
| 4. |  |
The reagent that is used to convert acetamide into methyl amine is:
1. NaOH-Br2
2. Soda lime
3. Hot conc. H2SO4
4. PCl5
The incorrect statement among the following regarding the primary amine is:
| 1. | Alkyl amines are stronger bases than aryl amines |
| 2. | Alkyl amines react with nitrous acid to produce alcohols |
| 3. | Aryl amines react with nitrous acid to produce phenols |
| 4. | Alkyl amines are stronger bases than ammonia |
© 2025 GoodEd Technologies Pvt. Ltd.