The equation of state of a gas is given by $\left(\mathrm{P}+\frac{{\mathrm{aT}}^{2}}{\mathrm{V}}\right){\mathrm{V}}^{\mathrm{c}}=\left(\mathrm{RT}+\mathrm{b}\right),$ where a, b, c and R are constants. The isotherms can be represented by $\mathrm{P}={\mathrm{AV}}^{\mathrm{m}}-{\mathrm{BV}}^{\mathrm{n}},$ where A and B depend only on temperature and

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