| Statement I: | Aniline does not undergo Friedel-Crafts alkylation reaction. |
| Statement II: | Aniline cannot be prepared through Gabriel synthesis. |
| 1. | Both Statement I and Statement II are incorrect. |
| 2. | Statement I is correct and Statement II is incorrect. |
| 3. | Statement I is incorrect and Statement II is correct. |
| 4. | Both Statement I and Statement II are correct. |

| List-I (Amine) |
List-II \(\textbf{(pK}_{b} ~\textbf{value}) \) |
||
| A. | Benzenamine | I. | 3.38 |
| B. | Phenylmethanamine | II. | 9.38 |
| C. | Methenamine | III. | 4.70 |
| D. | N-Ethylethanamine | IV. | 3.0 |
| 1. | A-II, B-III, C-I, D-IV | 2. | A-III, B-II, C-I, D-IV |
| 3. | A-II, B-I, C-III, D-IV | 4. | A-I, B-III, C-II, D-IV |
| List-I (Reagent) |
List-II (name of the reaction) |
||
| A. | Carbylamine test | I. | Phenol |
| B. | Bayer's test | II. | Acetone |
| C. | Iodoform test | III. | Ethylene |
| D. | Phthalein dye test | IV. | Aniline |
| Statement I: | Benzendiazonium chloride is a colourless crystalline solid. It is insoluble in water but reacts with water when warmed. |
| Statement II: | Benzendiazonium chloride on reacting with HCI in presence of copper powder gives chlorobenzene as the product. This is an example of Gatterman reaction. |
| 1. | Both Statement I and Statement II is true. |
| 2. | Both Statement I and Statement II is false. |
| 3. | Statement I is true but Statement II is false. |
| 4. | Statement I is false but Statement II is true. |
| 1. | NaNO2/HCl; Sn/HCl; Br2; H2O/H3PO2 |
| 2. | Sn/HCl; NaNO2/HCl; Br2; H2O/H3PO2 |
| 3. | Br2; Sn/HCl; NaNO2/HCl; H2O/H3PO2 |
| 4. | Sn/HCl; Br2; NaNO2/HCl; H2O/H3PO2 |
| 1. | 2. | ||
| 3. | 4. |
| 1. | 2. | ||
| 3. | 4. |
| 1. | |
| 2. | ![]() |
| 3. | ![]() |
| 4. | ![]() |
| Column-I (Reaction) |
Column-II (Product formed) |
||
| (a) | Gabriel synthesis | (i) | Benzaldehyde |
| (b) | Kolbe synthesis | (ii) | Ethers |
| (c) | Williamson synthesis | (iii) | Primary amines |
| (d) | Etard reaction | (iv) | Salicylic acid |
| (a) | (b) | (c) | (d) | |
| 1. | (iii) | (i) | (ii) | (iv) |
| 2. | (ii) | (iii) | (i) | (iv) |
| 3. | (iv) | (iii) | (i) | (ii) |
| 4. | (iii) | (iv) | (ii) | (i) |