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Which process does not occur during formation of CHCl3 from C2H5OH and bleaching powder?

1. Hydrolysis

2. Oxidation

3. Elimination

4. Chlorination

Subtopic:  Chemical Properties |
 51%
Level 3: 35%-60%
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Which of the following compounds undergo E2 reactions more easily?
 

1. \((CH_3)_2C.CH_2CH_3]\\ ~~~~~~~~~~~~~~|\\ ~~~~~~~~~~~~~Br\)
2. \(CH_3(CH_2)_2CH_2Cl\)
3. \(CH_3(CH_2)_2CH_2I\)
4. \(~~~~~~~~~~~~~~~~~~I\\ ~~~~~~~~~~~~~~~~~~|\\ (CH_3)_2-C-CH_2CH_3\)
Subtopic:  Chemical Properties |
 58%
Level 3: 35%-60%
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Which is most reactive for SN2 reactions ?

(1) CH3I

(2) C2H5I

(3) C3H7I

(4) C4H9I

Subtopic:  Chemical Properties |
 87%
Level 1: 80%+
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Which of the following options is correct?

1. CH3-CH=CH-CH3 predominates

2. CH2=CH-CH2-CH3 predominates

3. Both are formed in equal amounts

4. The product ratio is dependent on the halogen X

Subtopic:  Mechanism of Reactions |
 85%
Level 1: 80%+
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Ethylidene dichloride on treatment with aqueous KOH gives:

(1) CH3CHO

(2) CH2OH|CH2OH

(3) HCHO

(4) CHO|CHO

Subtopic:  Mechanism of Reactions |
Level 3: 35%-60%
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Mark the appropriate reagent used to distinguish vicinal and geminal dihalides.:

1. KOH (aq.) 2. KOH(alc.)
3. Zn dust 4. None of these
Subtopic:  Mechanism of Reactions |
Level 3: 35%-60%
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A compound A of formula C3H6Cl2 on reaction with alkali can give B of formula C3H6O or C of formula C3H4. B on oxidation gave a compound of the formula C3H6O2. C with dilute H2SOcontaining Hg2+ ion gave D of formula C3H6O, which with bromine and NaOH gave the sodium salt of C2H4O2. Then A is:

1. CH3CH2CHCl2

2. CH3CCl2CH3

3. CH3CHClCH2Cl

4. CH2ClCH2CH2Cl

Subtopic:  Mechanism of Reactions |
 58%
Level 3: 35%-60%
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Ethylene on treatment with chlorine gives:-

1. Ethylene dichloride

2. Ethylene chlorohydrin

3. CH4

4. C2H6

Subtopic:  Mechanism of Reactions |
 86%
Level 1: 80%+
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The compound A forms B with sodium metal and again A forms C with PCl5, but B and C form diethyl ether. Thus A, B and C are:

(1) C2H5OH, C2H5ONa , C2H5Cl

(2) C2H5OH, C2H5Cl, C2H5ONa

(3) C2H5OH, C2H5Cl, C2H4Cl2

(4) C2H5OH, C2H5Cl, C2H5OC2H5

Subtopic:  Mechanism of Reactions |
 81%
Level 1: 80%+
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The halide which undergoes nucleophilic substitution most readily is:

(1) p-H3CC6H4Cl

(2) o-H3COC6H4Cl

(3) p-ClC6H4Cl

(4) p-O2NC6H4Cl

Subtopic:  Mechanism of Reactions | Chemical Properties |
 69%
Level 2: 60%+
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