What is the decay constant (in days⁻¹) of a substance whose half-life is 77 days?

1. 0.9 2. 0.09
3. 0.009 4. 0.013

Subtopic:  First Order Reaction Kinetics |
 72%
Level 2: 60%+
AIPMT - 1999
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Consider the given reaction: 
\(H^{+}+BrO^-_3+3Br^- \rightarrow~5Br_2+H_2O\)
What is the correct representation of the consumption & formation of reactants and products?
1. d[Br-]dt=-35d[Br2]dt 2. d[Br-]dt=35d[Br2]dt
3. d[Br-]dt=-53d[Br2]dt 4. d[Br-]dt=53d[Br2]dt
Subtopic:  Definition, Rate Constant, Rate Law |
 74%
Level 2: 60%+
AIPMT - 2000
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92U235, nucleus absorb a neutron and disintegrate in 54Xe139, 38Sr94 and x . The product x is:

1. 3 - neutrons

2. 2 - neutrons

3. α - particle

4. β - particle

Subtopic:  First Order Reaction Kinetics |
Level 3: 35%-60%
AIPMT - 2002
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In the reaction, 3A2B the rate of reaction +d[B]dt  is equal to:-

1. -32d[A]dt

2. -23d[A]dt

3. -13d[A]dt

4. +2d[A]dt

Subtopic:  Definition, Rate Constant, Rate Law |
 89%
Level 1: 80%+
AIPMT - 2002
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2A  B + C; It would be a zero-order reaction when:

1. The rate of reaction is proportional to the square of the concentration of A
2. The rate of reaction remains the same at any concentration of A
3. The rate remains unchanged at any concentration of B and C
4. The rate of reaction doubles if the concentration of B is doubled
Subtopic:  Order, Molecularity and Mechanism |
 77%
Level 2: 60%+
AIPMT - 2002
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If at a given instant, for the reaction 2N2O→ 4NO2 + O2 rate and rate constant are 1.02 × 10-4  and 3.4 × 10-5 sec -1 respectively, then the concentration of N2O5 at that time will be: 

1. 1.732 

2. 3.0 

3. 1.02 × 10-4 

4. 3.4 × 105 

Subtopic:  Definition, Rate Constant, Rate Law |
 67%
Level 2: 60%+
AIPMT - 2001
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When a biochemical reaction is carried out in a laboratory outside the human body in the absence of an enzyme, then the rate of reaction obtained is 10-6 times. The activation energy of a reaction in the presence of an enzyme is:

1. 6RT
2. P is required.
3. Different from Ea obtained in the laboratory.
4. Data is insufficient.

Subtopic:  Arrhenius Equation |
 74%
Level 2: 60%+
AIPMT - 2001
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The activation energy for the forward reaction A → B is Ea.
Which of the following statements about the activation energy for the reverse reaction is correct?

1. It is the negative of Ea

2. It is always less than Ea

3. It can be less than or more than Ea

4. It is always double of Ea

Subtopic:  Arrhenius Equation |
 69%
Level 2: 60%+
AIPMT - 2003
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The reaction A → B follows first-order kinetics. The time taken for 0.8 mol of A to produce 0.6 mol of B is 1 hour. The time taken for the conversion of 0.9 mol of A to produce 0.675 mol of B will be: 

1. 1 hour 2. 0.5 hour
3. 0.25 hour 4. 2 hour
Subtopic:  First Order Reaction Kinetics |
 67%
Level 2: 60%+
AIPMT - 2003
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If the rate of the reaction is equal to the rate constant, the order of the reaction is:

1. 0 2. 1
3. 2 4. 3
Subtopic:  Order, Molecularity and Mechanism |
 86%
Level 1: 80%+
AIPMT - 2003
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